The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes
Open accessAbstract
Although silicon is a promising anode material for lithium-ion batteries, scalable synthesis of silicon anodes with good cyclability and low electrode swelling remains a significant challenge. Herein, we report a scalable top-down technique to produce ant-nest-like porous silicon from magnesium-silicon alloy. The ant-nest-like porous silicon comprising three-dimensional interconnected silicon nanoligaments and bicontinuous nanopores can prevent pulverization and accommodate volume expansion during cycling resulting in negligible particle-level outward expansion. The carbon-coated porous silicon anode delivers a high capacity of 1,271 mAh g−1 at 2,100 mA g−1 with 90% capacity retention after 1,000 cycles and has a low electrode swelling of 17.8% at a high areal capacity of 5.1 mAh cm−2. The full cell with the prelithiated silicon anode and Li(Ni 1/3 Co 1/3 Mn 1/3)O 2 cathode boasts a high energy density of 502 Wh Kg−1 and 84% capacity retention after 400 cycles. This work provides insights into the rational design of alloy anodes for high-energy batteries.
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Cites
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Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
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A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
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Cited by
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
A review of recent developments in Si/C composite materials for Li-ion batteries
Shi, Q., Zhou, J., Ullah, S., Yang, X., Tokarska, K., Trzebicka, B., Ta, H. Q., & Rümmeli, M. H. (2021) · Energy Storage Materials · doi:10.1016/j.ensm.2020.10.026 · Cited by 308
Nanostructuring versus microstructuring in battery electrodes
Jain, R., Lakhnot, A. S., Bhimani, K., Sharma, S., Mahajani, V., Panchal, R. A., Kamble, M., Han, F., Wang, C., & Koratkar, N. (2022) · Nature Reviews Materials · doi:10.1038/s41578-022-00454-9 · Cited by 298
Constructing Pure Si Anodes for Advanced Lithium Batteries
Je, M., Han, D.-Y., Ryu, J., & Park, S. (2023) · Accounts of Chemical Research · doi:10.1021/acs.accounts.3c00308 · Cited by 175
Metadata
- Authors
- An, W., Gao, B., Mei, S., Xiang, B., Fu, J., Wang, L., Zhang, Q., Chu, P. K., & Huo, K.
- Venue
- Nature Communications
- Published
- 2019-03-29
- Volume
- 10
- Issue
- 1
- Pages
- 1447-1447
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2933257952
- Cited by
- 785
- References
- 36
- FWCI
- 34.19
- Type
- journal article
- Language
- en
- Open access
- gold
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- An, W., Gao, B., Mei, S., Xiang, B., Fu, J., Wang, L., Zhang, Q., Chu, P. K., & Huo, K. (2019). Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes. Nature Communications. https://doi.org/10.1038/s41467-019-09510-5
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