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Layer-by-layer self-assembly of pillared two-dimensional multilayers

Open access
Tian, Weiqian, VahidMohammadi, Armin, Wang, Zhen, Ouyang, Liangqi, Beidaghi, Majid, Hamedi, Mahiar M.·2019·Nature Communications

Abstract

We report Layer-by-Layer (LbL) self-assembly of pillared two-dimensional (2D) multilayers, from water, onto a wide range of substrates. This LbL method uses a small molecule, tris(2-aminoethyl) amine (TAEA), and a colloidal dispersion of Ti 3 C 2 T x MXene to LbL self-assemble (MXene/TAEA)n multilayers, where n denotes the number of bilayers. Assembly with TAEA results in highly ordered (MXene/TAEA)n multilayers where the TAEA expands the interlayer spacing of MXene flakes by only ~ 1 Å and reinforces the interconnection between them. The TAEA-pillared MXene multilayers show the highest electronic conductivity of 7.3 × 10 4 S m−1 compared with all reported MXene multilayers fabricated by LbL technique. The (MXene/TAEA)n multilayers could be used as electrodes for flexible all-solid-state supercapacitors delivering a high volumetric capacitance of 583 F cm−3 and high energy and power densities of 3.0 Wh L−1 and 4400 W L−1, respectively. This strategy enables large-scale fabrication of highly conductive pillared MXene multilayers, and potentially fabrication of other 2D heterostructures.

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Metadata

Authors
Tian, W., VahidMohammadi, A., Wang, Z., Ouyang, L., Beidaghi, M., & Hamedi, M. M.
Venue
Nature Communications
Published
2019-06-11
Volume
10
Issue
1
Pages
2558-2558
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2949449262
Cited by
258
References
47
FWCI
10.85
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Layer-by-layer self-assembly of pillared two-dimensional multilayers. https://app.cochat.ai/papers/10.1038/s41467-019-10631-0
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Tian, W., VahidMohammadi, A., Wang, Z., Ouyang, L., Beidaghi, M., & Hamedi, M. M. (2019). Layer-by-layer self-assembly of pillared two-dimensional multilayers. Nature Communications. https://doi.org/10.1038/s41467-019-10631-0

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