The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Lead halide perovskites for photocatalytic organic synthesis
Open accessAbstract
Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C–C, C–O and C–N bond-forming reactions starting from CO 2 and light. Direct capture of solar energy for organic synthesis is a promising approach. Lead (Pb)-halide perovskite solar cells reach 24.2% power conversion efficiency, rendering perovskite a unique type material for solar energy capture. We argue that photophysical properties of perovskites already proved for photovoltaics, also should be of interest in photoredox organic synthesis. Because the key aspects of these two applications are both relying on charge separation and transfer. Here we demonstrated that perovskites nanocrystals are exceptional candidates as photocatalysts for fundamental organic reactions, for example C–C, C–N and C–O bond-formations. Stability of CsPbBr 3 in organic solvents and ease-of-tuning their bandedges garner perovskite a wider scope of organic substrate activations. Our low-cost, easy-to-process, highly-efficient, air-tolerant and bandedge-tunable perovskites may bring new breakthrough in organic chemistry.
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Cites
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
Burschka, J., Pellet, N., Moon, S.-J., Humphry-Baker, R., Gao, P., Nazeeruddin, M. K., & Grätzel, M. (2013) · Nature · doi:10.1038/nature12340 · Cited by 9,547
An empirical correction for absorption anisotropy
Blessing, R. H. (1995) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767394005726 · Cited by 7,928
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
Xing, G., Mathews, N., Sun, S., Lim, S. S., Lam, Y. M., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2013) · Science · doi:10.1126/science.1243167 · Cited by 6,909
Romero, N. A., & Nicewicz, D. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00057 · Cited by 6,283
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
Dong, Q., Fang, Y., Shao, Y., Mulligan, P., Qiu, J., Cao, L., & Huang, J. (2015) · Science · doi:10.1126/science.aaa5760 · Cited by 5,643
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
Saparov, B., & Mitzi, D. B. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00715 · Cited by 2,907
Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
Nicewicz, D. A., & MacMillan, D. W. C. (2008) · Science · doi:10.1126/science.1161976 · Cited by 2,489
Zhang, F., Zhong, H., Chen, C., Wu, X.-G., Hu, X., Huang, H., Han, J., Zou, B., & Dong, Y. (2015) · ACS Nano · doi:10.1021/acsnano.5b01154 · Cited by 2,431
Cited by
Heterogeneous Photocatalysis in Organic Synthesis
Gisbertz, S., & Pieber, B. (2020) · ChemPhotoChem · doi:10.1002/cptc.202000014 · Cited by 312
Dai, Y., Poidevin, C., Ochoa‐Hernández, C., Auer, A. A., & Tüysüz, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915034 · Cited by 269
Zhu, C., Yue, H., Jia, J., & Rueping, M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202013852 · Cited by 259
Metadata
- Authors
- Zhu, X., Lin, Y., San Martin, J., Sun, Y., Zhu, D., & Yan, Y.
- Venue
- Nature Communications
- Published
- 2019-06-28
- Volume
- 10
- Issue
- 1
- Pages
- 2843-2843
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2955361498
- Cited by
- 455
- References
- 43
- FWCI
- 17.98
- Type
- journal article
- Language
- en
- Open access
- gold
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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