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Highly efficient decomposition of ammonia using high-entropy alloy catalysts

Open access
Xie, Pengfei, Yao, Yonggang, Huang, Zhennan, Liu, Zhenyu, Zhang, Junlei, Li, Tangyuan, Wang, Guofeng, Shahbazian-Yassar, Reza, Hu, Liangbing, Wang, Chao·2019·Nature Communications

Abstract

Ammonia represents a promising liquid fuel for hydrogen storage, but its large-scale application is limited by the need for precious metal ruthenium (Ru) as catalyst. Here we report on highly efficient ammonia decomposition using novel high-entropy alloy (HEA) catalysts made of earth abundant elements. Quinary CoMoFeNiCu nanoparticles are synthesized in a single solid-solution phase with robust control over the Co/Mo atomic ratio, including those ratios considered to be immiscible according to the Co-Mo bimetallic phase diagram. These HEA nanoparticles demonstrate substantially enhanced catalytic activity and stability for ammonia decomposition, with improvement factors achieving >20 versus Ru catalysts. Catalytic activity of HEA nanoparticles is robustly tunable by varying the Co/Mo ratio, allowing for the optimization of surface property to maximize the reactivity under different reaction conditions. Our work highlights the great potential of HEAs for catalyzing chemical transformation and energy conversion reactions.

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Metadata

Authors
Xie, P., Yao, Y., Huang, Z., Liu, Z., Zhang, J., Li, T., Wang, G., Shahbazian-Yassar, R., Hu, L., & Wang, C.
Venue
Nature Communications
Published
2019-09-05
Volume
10
Issue
1
Pages
4011-4011
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2972052805
Cited by
813
References
4
FWCI
12.41
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Highly efficient decomposition of ammonia using high-entropy alloy catalysts. https://app.cochat.ai/papers/10.1038/s41467-019-11848-9
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Xie, P., Yao, Y., Huang, Z., Liu, Z., Zhang, J., Li, T., Wang, G., Shahbazian-Yassar, R., Hu, L., & Wang, C. (2019). Highly efficient decomposition of ammonia using high-entropy alloy catalysts. Nature Communications. https://doi.org/10.1038/s41467-019-11848-9

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