The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Highly efficient decomposition of ammonia using high-entropy alloy catalysts
Open accessAbstract
Ammonia represents a promising liquid fuel for hydrogen storage, but its large-scale application is limited by the need for precious metal ruthenium (Ru) as catalyst. Here we report on highly efficient ammonia decomposition using novel high-entropy alloy (HEA) catalysts made of earth abundant elements. Quinary CoMoFeNiCu nanoparticles are synthesized in a single solid-solution phase with robust control over the Co/Mo atomic ratio, including those ratios considered to be immiscible according to the Co-Mo bimetallic phase diagram. These HEA nanoparticles demonstrate substantially enhanced catalytic activity and stability for ammonia decomposition, with improvement factors achieving >20 versus Ru catalysts. Catalytic activity of HEA nanoparticles is robustly tunable by varying the Co/Mo ratio, allowing for the optimization of surface property to maximize the reactivity under different reaction conditions. Our work highlights the great potential of HEAs for catalyzing chemical transformation and energy conversion reactions.
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Cited by
Oses, C., Toher, C., & Curtarolo, S. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0170-8 · Cited by 2,081
High-entropy nanoparticles: Synthesis-structure-property relationships and data-driven discovery
Yao, Y., Dong, Q., Brozena, A., Luo, J., Miao, J., Chi, M., Wang, C., Kevrekidis, I. G., Ren, Z. J., Greeley, J., et al. (2022) · Science · doi:10.1126/science.abn3103 · Cited by 1,081
Self-citationHigh-entropy energy materials: challenges and new opportunities
Ma, Y., Ma, Y., Wang, Q., Schweidler, S., Botros, M., Fu, T., Hahn, H., Brezesinski, T., & Breitung, B. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00505g · Cited by 963
High-entropy materials for catalysis: A new frontier
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(2020) · doi:10.1038/s41467-020-19277-9 · Cited by 690
Metadata
- Authors
- Xie, P., Yao, Y., Huang, Z., Liu, Z., Zhang, J., Li, T., Wang, G., Shahbazian-Yassar, R., Hu, L., & Wang, C.
- Venue
- Nature Communications
- Published
- 2019-09-05
- Volume
- 10
- Issue
- 1
- Pages
- 4011-4011
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2972052805
- Cited by
- 813
- References
- 4
- FWCI
- 12.41
- Type
- journal article
- Language
- en
- Open access
- gold
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