The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Molecular cobalt corrole complex for the heterogeneous electrocatalytic reduction of carbon dioxide
Open accessAbstract
Electrochemical conversion of CO 2 to alcohols is one of the most challenging methods of conversion and storage of electrical energy in the form of high-energy fuels. The challenge lies in the catalyst design to enable its real-life implementation. Herein, we demonstrate the synthesis and characterization of a cobalt(III) triphenylphosphine corrole complex, which contains three polyethylene glycol residues attached at the meso-phenyl groups. Electron-donation and therefore reduction of the cobalt from cobalt(III) to cobalt(I) is accompanied by removal of the axial ligand, thus resulting in a square-planar cobalt(I) complex. The cobalt(I) as an electron-rich supernucleophilic d 8-configurated metal centre, where two electrons occupy and fill up the antibonding d z2 orbital. This orbital possesses high affinity towards electrophiles, allowing for such electronically configurated metals reactions with carbon dioxide. Herein, we report the potential dependent heterogeneous electroreduction of CO 2 to ethanol or methanol of an immobilized cobalt A 3-corrole catalyst system. In moderately acidic aqueous medium (pH = 6.0), the cobalt corrole modified carbon paper electrode exhibits a Faradaic Efficiency (FE%) of 48 % towards ethanol production.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
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New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Cited by
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Electrochemical hydrogenation and oxidation of organic species involving water
Liu, C., Chen, F., Zhao, B.-H., Wu, Y., & Zhang, B. (2024) · Nature Reviews Chemistry · doi:10.1038/s41570-024-00589-z · Cited by 269
Metadata
- Authors
- Gonglach, S., Paul, S., Haas, M., Pillwein, F., Sreejith, S. S., Barman, S., De, R., Müllegger, S., Gerschel, P., Apfel, U.-P., Coskun, H., Aljabour, A., Stadler, P., Schöfberger, W., & Roy, S.
- Venue
- Nature Communications
- Published
- 2019-08-27
- Volume
- 10
- Issue
- 1
- Pages
- 3864-3864
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2970495233
- Cited by
- 198
- References
- 9
- FWCI
- 4.28
- Type
- journal article
- Language
- en
- Open access
- gold
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- Gonglach, S., Paul, S., Haas, M., Pillwein, F., Sreejith, S. S., Barman, S., De, R., Müllegger, S., Gerschel, P., Apfel, U.-P., Coskun, H., Aljabour, A., Stadler, P., Schöfberger, W., & Roy, S. (2019). Molecular cobalt corrole complex for the heterogeneous electrocatalytic reduction of carbon dioxide. Nature Communications. https://doi.org/10.1038/s41467-019-11868-5
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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