The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution
Open accessAbstract
Metal–support interaction is of great significance for catalysis as it can induce charge transfer between metal and support, tame electronic structure of supported metals, impact adsorption energy of reaction intermediates, and eventually change the catalytic performance. Here, we report the metal size-dependent charge transfer reversal, that is, electrons transfer from platinum single atoms to sulfur-doped carbons and the carbon supports conversely donate electrons to Pt when their size is expanded to ~1.5 nm cluster. The electron-enriched Pt nanoclusters are far more active than electron-deficient Pt single atoms for catalyzing hydrogen evolution reaction, exhibiting only 11 mV overpotential at 10 mA cm−2 and a high mass activity of 26.1 A mg−1 at 20 mV, which is 38 times greater than that of commercial Pt/C. Our work manifests that the manipulation of metal size-dependent charge transfer between metal and support opens new avenues for developing high-active catalysts.
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Cited by
Shi, Y., Ma, Z.-R., Xiao, Y.-Y., Yin, Y.-C., Huang, W.-M., Huang, Z.-C., Zheng, Y.-Z., Mu, F.-Y., Huang, R., Shi, G.-Y., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-23306-6 · Cited by 894
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Jiang, K., Luo, M., Liu, Z., Peng, M., Chen, D., Lu, Y.-R., Chan, T.-S., de Groot, F. M. F., & Tan, Y. (2021) · Nature Communications · doi:10.1038/s41467-021-21956-0 · Cited by 411
Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination
Lu, B., Liu, Q., & Chen, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01950 · Cited by 394
Metadata
- Authors
- Yan, Q.-Q., Wu, D.-X., Chu, S.-Q., Chen, Z.-Q., Lin, Y., Chen, M.-X., Zhang, J., Wu, X.-J., & Liang, H.-W.
- Venue
- Nature Communications
- Published
- 2019-10-31
- Volume
- 10
- Issue
- 1
- Pages
- 4977-4977
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2982521228
- Cited by
- 444
- References
- 16
- FWCI
- 7.94
- Type
- journal article
- Language
- en
- Open access
- gold
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- Yan, Q.-Q., Wu, D.-X., Chu, S.-Q., Chen, Z.-Q., Lin, Y., Chen, M.-X., Zhang, J., Wu, X.-J., & Liang, H.-W. (2019). Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution. Nature Communications. https://doi.org/10.1038/s41467-019-12851-w
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