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Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction

Open access
Zhang, Lei, Si, Rutong, Liu, Hanshuo, Chen, Ning, Wang, Qi, Adair, Keegan, Wang, Zhiqiang, Chen, Jiatang, Song, Zhongxin, Li, Junjie, Banis, Mohammad Norouzi, Li, Ruying, Sham, Tsun-Kong, Gu, Meng, Liu, Li-Min, Botton, Gianluigi A., Sun, Xueliang·2019·Nature Communications

Abstract

Single atom catalysts exhibit particularly high catalytic activities in contrast to regular nanomaterial-based catalysts. Until recently, research has been mostly focused on single atom catalysts, and it remains a great challenge to synthesize bimetallic dimer structures. Herein, we successfully prepare high-quality one-to-one A-B bimetallic dimer structures (Pt-Ru dimers) through an atomic layer deposition (ALD) process. The Pt-Ru dimers show much higher hydrogen evolution activity (more than 50 times) and excellent stability compared to commercial Pt/C catalysts. X-ray absorption spectroscopy indicates that the Pt-Ru dimers structure model contains one Pt-Ru bonding configuration. First principle calculations reveal that the Pt-Ru dimer generates a synergy effect by modulating the electronic structure, which results in the enhanced hydrogen evolution activity. This work paves the way for the rational design of bimetallic dimers with good activity and stability, which have a great potential to be applied in various catalytic reactions.

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Metadata

Authors
Zhang, L., Si, R., Liu, H., Chen, N., Wang, Q., Adair, K., Wang, Z., Chen, J., Song, Z., Li, J., Banis, M. N., Li, R., Sham, T.-K., Gu, M., Liu, L.-M., Botton, G. A., & Sun, X.
Venue
Nature Communications
Published
2019-10-30
Volume
10
Issue
1
Pages
4936-4936
ISSN
2041-1723 (ISSN-L)
OpenAlex
W2982659300
Cited by
600
References
50
FWCI
12.83
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction. https://app.cochat.ai/papers/10.1038/s41467-019-12887-y
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Zhang, L., Si, R., Liu, H., Chen, N., Wang, Q., Adair, K., Wang, Z., Chen, J., Song, Z., Li, J., Banis, M. N., Li, R., Sham, T.-K., Gu, M., Liu, L.-M., Botton, G. A., & Sun, X. (2019). Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction. Nature Communications. https://doi.org/10.1038/s41467-019-12887-y

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