The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Photoinduced hydrogen release from hydrogen boride sheets
Abstract
Hydrogen boride nanosheets (HB sheets) are facilely synthesized via ion-exchange treatment on magnesium diboride (MgB 2 ) in an acetonitrile solution. Optical absorption and fluorescence spectra of HB sheets indicate that their bandgap energy is 2.8 eV. According to first-principles calculations, optical absorption seen at 2.8 eV is assigned to the electron transition between the σ-bonding states of B and H orbitals. In addition, density functional theory (DFT) calculations suggest the other allowed transition from the σ-bonding state of B and H orbitals to the antibonding state with the gap of 3.8 eV. Significant gaseous H 2 release is found to occur only under photoirradiation, which causes the electron transition from the σ-bonding state to the antibonding state even under mild ambient conditions. The amount of H 2 released from the irradiated HB sheets is estimated to be 8 wt%, indicating that the sheets have a high H 2 -storage capacity compared with previously reported metal H 2 -storage materials.
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Cited by
Chemical stability of hydrogen boride nanosheets in water
Rojas, K. I. M., Cuong, N. T., Nishino, H., Ishibiki, R., Ito, S.-I., Miyauchi, M., Fujimoto, Y., Tominaka, S., Okada, S., Hosono, H., et al. (2021) · Communications Materials · doi:10.1038/s43246-021-00184-5 · Cited by 40
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Metadata
- Authors
- Kawamura, R., Cuong, N. T., Fujita, T., Ishibiki, R., Hirabayashi, T., Yamaguchi, A., Matsuda, I., Okada, S., Kondo, T., & Miyauchi, M.
- Venue
- Nature Communications
- Published
- 2019-10-25
- Volume
- 10
- Issue
- 1
- ISSN
- 2041-1723
- Cited by
- 115
- References
- 32
- Language
- en
- Licence
- creativecommons.org/licenses/by/4.0 (tdm)
- creativecommons.org/licenses/by/4.0 (vor)
- Funders
- MEXT | Japan Society for the Promotion of Science (18H02055)
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