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Cited by 40

The DOI matches its Crossref record; 51 of the 51 references it cites were found in a registry or an index.

Chemical stability of hydrogen boride nanosheets in water

Rojas, Kurt Irvin M., Cuong, Nguyen Thanh, Nishino, Hiroaki, Ishibiki, Ryota, Ito, Shin-ichi, Miyauchi, Masahiro, Fujimoto, Yoshitaka, Tominaka, Satoshi, Okada, Susumu, Hosono, Hideo, Arboleda, Nelson B., Kondo, Takahiro, Morikawa, Yoshitada, Hamada, Ikutaro·2021·Communications Materials
DOI 10.1038/s43246-021-00184-5
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Abstract

Boron-based two-dimensional materials are of interest for use in electronic devices and catalytic applications, for which it is important that they are chemically stable. Here, we explore the chemical stability of hydrogen boride nanosheets in water. Experiments reveal that mixing hydrogen boride and water produces negligible amounts of hydrogen, suggesting that hydrolysis does not occur and that hydrogen boride is stable in water, which is in contrast to most boron hydride materials. First-principles calculations reveal that the sheets interact weakly with water even in the presence of defects and that negatively charged boron prevents the onset of hydrolysis. We conclude that the charge state of boron and the covalent boron-boron bond network are responsible for the chemical and structural stability. On the other hand, we found that proton exchange with hydrogen boride nanosheets does occur in water, indicating that they become acidic in the presence of water.

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Research works printed but not linked: 1

  1. Rojas, K. I. M. et al. Chemical stability of hydrogen boride nanosheets in water. Materials Cloud Archive 2021.87 https://doi.org/10.24435/materialscloud:40-28 (2021). · DOI

Metadata

Authors
Rojas, K. I. M., Cuong, N. T., Nishino, H., Ishibiki, R., Ito, S.-I., Miyauchi, M., Fujimoto, Y., Tominaka, S., Okada, S., Hosono, H., Arboleda, N. B., Kondo, T., Morikawa, Y., & Hamada, I.
Venue
Communications Materials
Publisher
Springer Science and Business Media LLC
Published
2021-07-23
Volume
2
Issue
1
ISSN
2662-4443
DOI
10.1038/s43246-021-00184-5
Cited by
40
References
51
Language
en
Licence
Funders
  • DOST | National Research Council of the Philippines
  • MEXT | Japan Society for the Promotion of Science (JP18K18989, JP19H02551, JP19H05046, JP21H00015, JPMXP0112101001, JP20H02569, JP18H05519)
  • Kumagai Foundation for Science and Technology
  • Ogasawara Foundation for the Promotion of Science and Engineering
  • - Samco foundations for the Promotion of Science & Engineering - MHI Innovation Accelerator LLC
  • The Tokyo Electron Ltd

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CoChat. (2026). Citation check: Chemical stability of hydrogen boride nanosheets in water. https://app.cochat.ai/papers/10.1038/s43246-021-00184-5
The paper
Rojas, K. I. M., Cuong, N. T., Nishino, H., Ishibiki, R., Ito, S.-I., Miyauchi, M., Fujimoto, Y., Tominaka, S., Okada, S., Hosono, H., Arboleda, N. B., Kondo, T., Morikawa, Y., & Hamada, I. (2021). Chemical stability of hydrogen boride nanosheets in water. Communications Materials. https://doi.org/10.1038/s43246-021-00184-5

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.