The DOI matches its Crossref record; 56 of the 56 references it cites were found in a registry or an index.
A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering
Open accessAbstract
First-row transition metal-based catalysts have been developed for the oxygen evolution reaction (OER) during the past years, however, such catalysts typically operate at overpotentials (η) significantly above thermodynamic requirements. Here, we report an iron/nickel terephthalate coordination polymer on nickel form (NiFeCP/NF) as catalyst for OER, in which both coordinated and uncoordinated carboxylates were maintained after electrolysis. NiFeCP/NF exhibits outstanding electro-catalytic OER activity with a low overpotential of 188 mV at 10 mA cm−2 in 1.0 KOH, with a small Tafel slope and excellent stability. The pH-independent OER activity of NiFeCP/NF on the reversible hydrogen electrode scale suggests that a concerted proton-coupled electron transfer (c-PET) process is the rate-determining step (RDS) during water oxidation. Deuterium kinetic isotope effects, proton inventory studies and atom-proton-transfer measurements indicate that the uncoordinated carboxylates are serving as the proton transfer relays, with a similar function as amino acid residues in photosystem II (PSII), accelerating the proton-transfer rate.
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Cites
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
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Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting
Friebel, D., Louie, M. W., Bajdich, M., Sanwald, K. E., Cai, Y., Wise, A. M., Cheng, M.-J., Sokaras, D., Weng, T.-C., Alonso-Mori, R., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/ja511559d · Cited by 2,732
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
Zhao, S., Wang, Y., Dong, J., He, C.-T., Yin, H., An, P., Zhao, K., Zhang, X., Gao, C., Zhang, L., et al. (2016) · Nature Energy · doi:10.1038/nenergy.2016.184 · Cited by 2,602
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution
Grimaud, A., Diaz-Morales, O., Han, B., Hong, W. T., Lee, Y.-L., Giordano, L., Stoerzinger, K. A., Koper, M. T. M., & Shao-Horn, Y. (2017) · Nature Chemistry · doi:10.1038/nchem.2695 · Cited by 2,530
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Cited by
Yu, M., Budiyanto, E., & Tüysüz, H. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202103824 · Cited by 771
Huang, J., Sheng, H., Ross, R. D., Han, J., Wang, X., Song, B., & Jin, S. (2021) · Nature Communications · doi:10.1038/s41467-021-23390-8 · Cited by 707
Metal–organic frameworks and their derivatives as electrocatalysts for the oxygen evolution reaction
Du, J., Li, F., & Sun, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01191f · Cited by 578
Self-citationDai, J., Zhu, Y., Chen, Y., Wen, X., Long, M., Wu, X., Hu, Z., Guan, D., Wang, X., Zhou, C., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-28843-2 · Cited by 467
Self-citationLi, C., Xie, L., Zhao, J., Gu, L., Tang, H., Zheng, L., & Li, G. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202116934 · Cited by 396
Metadata
- Authors
- Li, W., Li, F., Yang, H., Wu, X., Zhang, P., Shan, Y., & Sun, L.
- Venue
- Nature Communications
- Published
- 2019-11-07
- Volume
- 10
- Issue
- 1
- Pages
- 5074-5074
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2986778178
- Cited by
- 408
- References
- 56
- FWCI
- 7.11
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, W., Li, F., Yang, H., Wu, X., Zhang, P., Shan, Y., & Sun, L. (2019). A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering. Nature Communications. https://doi.org/10.1038/s41467-019-13052-1
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