The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks
Open accessAbstract
Highly effective electrocatalysts promoting CO 2 reduction reaction (CO 2 RR) is extremely desirable to produce value-added chemicals/fuels while addressing current environmental challenges. Herein, we develop a layer-stacked, bimetallic two-dimensional conjugated metal-organic framework (2D c-MOF) with copper-phthalocyanine as ligand (CuN 4) and zinc-bis(dihydroxy) complex (ZnO 4) as linkage (PcCu-O 8-Zn). The PcCu-O 8-Zn exhibits high CO selectivity of 88%, turnover frequency of 0.39 s−1 and long-term durability (>10 h), surpassing thus by far reported MOF-based electrocatalysts. The molar H 2/CO ratio (1:7 to 4:1) can be tuned by varying metal centers and applied potential, making 2D c-MOFs highly relevant for syngas industry applications. The contrast experiments combined with operando spectroelectrochemistry and theoretical calculation unveil a synergistic catalytic mechanism; ZnO 4 complexes act as CO 2 RR catalytic sites while CuN 4 centers promote the protonation of adsorbed CO 2 during CO 2 RR. This work offers a strategy on developing bimetallic MOF electrocatalysts for synergistically catalyzing CO 2 RR toward syngas synthesis.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
1 retracted
Zheng, X., Ji, Y., Tang, J., Wang, J., Liu, B., Steinrück, H.-G., Lim, K., Li, Y., Toney, M. F., Chan, K., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0200-8 · Cited by 286
RetractedGeneralized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Ab initio molecular dynamics for liquid metals
Kresse, G., & Hafner, J. (1993) · Physical Review B · doi:10.1103/physrevb.47.558 · Cited by 45,727
Semiempirical GGA‐type density functional constructed with a long‐range dispersion correction
Grimme, S. (2006) · Journal of Computational Chemistry · doi:10.1002/jcc.20495 · Cited by 31,038
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
Lin, S., Diercks, C. S., Zhang, Y.-B., Kornienko, N., Nichols, E. M., Zhao, Y., Paris, A. R., Kim, D., Yang, P., Yaghi, O. M., et al. (2015) · Science · doi:10.1126/science.aac8343 · Cited by 2,644
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Two-dimensional metal–organic framework nanosheets: synthesis and applications
Zhao, M., Huang, Y., Peng, Y., Huang, Z., Ma, Q., & Zhang, H. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00268a · Cited by 1,348
Cited by
Multi‐Sites Electrocatalysis in High‐Entropy Alloys
Li, H., Lai, J., Li, Z., & Wang, L. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202106715 · Cited by 494
Jiao, L., Yang, W., Wan, G., Zhang, R., Zheng, X., Zhou, H., Yu, S., & Jiang, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202008787 · Cited by 412
Zhang, L., Li, X.-X., Lang, Z.-L., Liu, Y., Liu, J., Yuan, L., Lu, W.-Y., Xia, Y.-S., Dong, L.-Z., Yuan, D.-Q., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c11450 · Cited by 292
Engineering Strategies for Suppressing the Shuttle Effect in Lithium–Sulfur Batteries
Li, J., Gao, L., Pan, F., Gong, C., Sun, L., Gao, H., Zhang, J., Zhao, Y., Wang, G., & Liu, H. (2024) · Nano-Micro Letters · doi:10.1007/s40820-023-01223-1 · Cited by 267
Self-citationWei, Y., Sun, L., Wang, M., Hong, J., Zou, L., Liu, H., Wang, Y., Zhang, M., Liu, Z., Li, Y., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202007221 · Cited by 253
Self-citation
Metadata
- Authors
- Zhong, H., Ghorbani-Asl, M., Ly, K. H., Zhang, J., Ge, J., Wang, M., Liao, Z., Makarov, D., Zschech, E., Brunner, E., Weidinger, I. M., Zhang, J., Krasheninnikov, A. V., Kaskel, S., Dong, R., & Feng, X.
- Venue
- Nature Communications
- Published
- 2020-03-16
- Volume
- 11
- Issue
- 1
- Pages
- 1409-1409
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3012118139
- Cited by
- 517
- References
- 50
- FWCI
- 15.47
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks. https://app.cochat.ai/papers/10.1038/s41467-020-15141-y
- The paper
- Zhong, H., Ghorbani-Asl, M., Ly, K. H., Zhang, J., Ge, J., Wang, M., Liao, Z., Makarov, D., Zschech, E., Brunner, E., Weidinger, I. M., Zhang, J., Krasheninnikov, A. V., Kaskel, S., Dong, R., & Feng, X. (2020). Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks. Nature Communications. https://doi.org/10.1038/s41467-020-15141-y
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
