The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation
Open accessAbstract
The development of oxygen evolution reaction (OER) electrocatalysts remains a major challenge that requires significant advances in both mechanistic understanding and material design. Recent studies show that oxygen from the perovskite oxide lattice could participate in the OER via a lattice oxygen-mediated mechanism, providing possibilities for the development of alternative electrocatalysts that could overcome the scaling relations-induced limitations found in conventional catalysts utilizing the adsorbate evolution mechanism. Here we distinguish the extent to which the participation of lattice oxygen can contribute to the OER through the rational design of a model system of silicon-incorporated strontium cobaltite perovskite electrocatalysts with similar surface transition metal properties yet different oxygen diffusion rates. The as-derived silicon-incorporated perovskite exhibits a 12.8-fold increase in oxygen diffusivity, which matches well with the 10-fold improvement of intrinsic OER activity, suggesting that the observed activity increase is dominantly a result of the enhanced lattice oxygen participation.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Chen, F.-Y., Wu, Z.-Y., Adler, Z., & Wang, H. (2021) · Joule · doi:10.1016/j.joule.2021.05.005 · Cited by 1,284
Self-citationZhao, Y., Adiyeri Saseendran, D. P., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00515 · Cited by 802
Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis
He, Z., Zhang, J., Gong, Z., Lei, H., Zhou, D., Zhang, N., Mai, W., Zhao, S., & Chen, Y. (2022) · Nature Communications · doi:10.1038/s41467-022-29875-4 · Cited by 665
Self-citationShi, Z., Wang, Y., Li, J., Wang, X., Wang, Y., Li, Y., Xu, W., Jiang, Z., Liu, C., Xing, W., et al. (2021) · Joule · doi:10.1016/j.joule.2021.05.018 · Cited by 554
Metadata
- Authors
- Pan, Y., Xu, X., Zhong, Y., Ge, L., Chen, Y., Veder, J.-P. M., Guan, D., O’Hayre, R., Li, M., Wang, G., Wang, H., Zhou, W., & Shao, Z.
- Venue
- Nature Communications
- Published
- 2020-04-24
- Volume
- 11
- Issue
- 1
- Pages
- 2002-2002
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3020542478
- Cited by
- 726
- References
- 3
- FWCI
- 17.15
- Type
- journal article
- Language
- en
- Open access
- gold
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