The DOI matches its Crossref record; 767 of the 767 references it cites were found in a registry or an index.
Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design
Abstract
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of various energy conversion and storage systems. However, their sluggish reaction kinetics, i.e., the demanding multielectron transfer processes, still render OER/ORR catalysts less efficient for practical applications. Moreover, the complexity of the catalyst–electrolyte interface makes a comprehensive understanding of the intrinsic OER/ORR mechanisms challenging. Fortunately, recent advances of in situ / operando characterization techniques have facilitated the kinetic monitoring of catalysts under reaction conditions. Here we provide selected highlights of recent in situ / operando mechanistic studies of OER/ORR catalysts with the main emphasis placed on heterogeneous systems (primarily discussing first-row transition metals which operate under basic conditions), followed by a brief outlook on molecular catalysts. Key sections in this review are focused on determination of the true active species, identification of the active sites, and monitoring of the reactive intermediates. For in-depth insights into the above factors, a short overview of the metrics for accurate characterizations of OER/ORR catalysts is provided. A combination of the obtained time-resolved reaction information and reliable activity data will then guide the rational design of new catalysts. Strategies such as optimizing the restructuring process as well as overcoming the adsorption-energy scaling relations will be discussed. Finally, pending current challenges and prospects toward the understanding and development of efficient heterogeneous catalysts and selected homogeneous catalysts are presented.
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Cites
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Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Unlocking Efficiency: Minimizing Energy Loss in Electrocatalysts for Water Splitting
Li, W., Liu, Y., Azam, A., Liu, Y., Yang, J., Wang, D., Sorrell, C. C., Zhao, C., & Li, S. (2024) · Advanced Materials · doi:10.1002/adma.202404658 · Cited by 162
Deformable Catalytic Material Derived from Mechanical Flexibility for Hydrogen Evolution Reaction
Wang, F., Xie, L., Sun, N., Zhi, T., Zhang, M., Liu, Y., Luo, Z., Yi, L., Zhao, Q., & Wang, L. (2024) · Nano-Micro Letters · doi:10.1007/s40820-023-01251-x · Cited by 36
Metadata
- Authors
- Zhao, Y., Adiyeri Saseendran, D. P., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-03-21
- Volume
- 123
- Issue
- 9
- Pages
- 6257-6358
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W4328051836
- Cited by
- 802
- References
- 767
- FWCI
- 13.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, Y., Adiyeri Saseendran, D. P., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R. (2023). Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.2c00515
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