The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
d-Orbital steered active sites through ligand editing on heterometal imidazole frameworks for rechargeable zinc-air battery
Open accessAbstract
The implementation of pristine metal-organic frameworks as air electrode may spark fresh vitality to rechargeable zinc-air batteries, but successful employment is rare due to the challenges in regulating their electronic states and structural porosity. Here we conquer these issues by incorporating ligand vacancies and hierarchical pores into cobalt-zinc heterometal imidazole frameworks. Systematic characterization and theoretical modeling disclose that the ligand editing eases surmountable energy barrier for *OH deprotonation by its efficacy to steer metal d-orbital electron occupancy. As a stride forward, the selected cobalt-zinc heterometallic alliance lifts the energy level of unsaturated d-orbitals and optimizes their adsorption/desorption process with oxygenated intermediates. With these merits, cobalt-zinc heterometal imidazole frameworks, as a conceptually unique electrode, empowers zinc-air battery with a discharge-charge voltage gap of 0.8 V and a cyclability of 1250 h at 15 mA cm–2, outperforming the noble-metal benchmarks.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Choi, J.-Y., Yang, L., Kishimoto, T., Fu, X., Ye, S., Chen, Z., & Banham, D. (2017) · Energy & Environmental Science · doi:10.1039/c6ee03005j · Cited by 162
Self-citation
Cited by
Zn-based batteries for sustainable energy storage: strategies and mechanisms
Tang, L., Peng, H., Kang, J., Chen, H., Zhang, M., Liu, Y., Kim, D. H., Liu, Y., & Lin, Z. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00295k · Cited by 548
Recent Advances of Aqueous Rechargeable Zinc‐Iodine Batteries: Challenges, Solutions, and Prospects
Lin, D., & Li, Y. (2022) · Advanced Materials · doi:10.1002/adma.202108856 · Cited by 470
Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries
Ye, Z., Jiang, Y., Li, L., Wu, F., & Chen, R. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00726-z · Cited by 323
Self-citationDo, V.-H., & Lee, J.-M. (2022) · ACS Nano · doi:10.1021/acsnano.2c08919 · Cited by 292
Engineering 3d–2p–4f Gradient Orbital Coupling to Enhance Electrocatalytic Oxygen Reduction
Wang, X., Wang, J., Wang, P., Li, L., Zhang, X., Sun, D., Li, Y., Tang, Y., Wang, Y., & Fu, G. (2022) · Advanced Materials · doi:10.1002/adma.202206540 · Cited by 266
Metadata
- Authors
- Jiang, Y., Deng, Y.-P., Liang, R., Fu, J., Gao, R., Luo, D., Bai, Z., Hu, Y., Yu, A., & Chen, Z.
- Venue
- Nature Communications
- Published
- 2020-11-17
- Volume
- 11
- Issue
- 1
- Pages
- 5858-5858
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3105677887
- Cited by
- 175
- References
- 2
- FWCI
- 4.91
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: d-Orbital steered active sites through ligand editing on heterometal imidazole frameworks for rechargeable zinc-air battery. https://app.cochat.ai/papers/10.1038/s41467-020-19709-6
- The paper
- Jiang, Y., Deng, Y.-P., Liang, R., Fu, J., Gao, R., Luo, D., Bai, Z., Hu, Y., Yu, A., & Chen, Z. (2020). d-Orbital steered active sites through ligand editing on heterometal imidazole frameworks for rechargeable zinc-air battery. Nature Communications. https://doi.org/10.1038/s41467-020-19709-6
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
