The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution
Open accessAbstract
Construction of Z-scheme heterostructure is of great significance for realizing efficient photocatalytic water splitting. However, the conscious modulation of Z-scheme charge transfer is still a great challenge. Herein, interfacial Mo-S bond and internal electric field modulated Z-scheme heterostructure composed by sulfur vacancies-rich ZnIn 2 S 4 and MoSe 2 was rationally fabricated for efficient photocatalytic hydrogen evolution. Systematic investigations reveal that Mo-S bond and internal electric field induce the Z-scheme charge transfer mechanism as confirmed by the surface photovoltage spectra, DMPO spin-trapping electron paramagnetic resonance spectra and density functional theory calculations. Under the intense synergy among the Mo-S bond, internal electric field and S-vacancies, the optimized photocatalyst exhibits high hydrogen evolution rate of 63.21 mmol∙g −1 ·h −1 with an apparent quantum yield of 76.48% at 420 nm monochromatic light, which is about 18.8-fold of the pristine ZIS. This work affords a useful inspiration on consciously modulating Z-scheme charge transfer by atomic-level interface control and internal electric field to signally promote the photocatalytic performance.
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Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Yu, P., Wang, F., Shifa, T. A., Zhan, X., Lou, X., Xia, F., & He, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.01.017 · Cited by 434
Gu, Y., Wu, A., Jiao, Y., Zheng, H., Wang, X., Xie, Y., Wang, L., Tian, C., & Fu, H. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202016102 · Cited by 363
Self-citation
Cited by
Recent Progress of Metal Sulfide Photocatalysts for Solar Energy Conversion
Zhu, Q., Xu, Q., Du, M., Zeng, X., Zhong, G., Qiu, B., & Zhang, J. (2022) · Advanced Materials · doi:10.1002/adma.202202929 · Cited by 423
ZnIn2S4‐Based Photocatalysts for Energy and Environmental Applications
Yang, R., Mei, L., Fan, Y., Zhang, Q., Zhu, R., Amal, R., Yin, Z., & Zeng, Z. (2021) · Small Methods · doi:10.1002/smtd.202100887 · Cited by 319
Induced dipole moments in amorphous ZnCdS catalysts facilitate photocatalytic H2 evolution
Wang, X., Liu, B., Ma, S., Zhang, Y., Wang, L., Zhu, G., Huang, W., & Wang, S. (2024) · Nature Communications · doi:10.1038/s41467-024-47022-z · Cited by 299
Self-citationLiu, W., Wang, P., Ao, Y., Chen, J., Gao, X., Jia, B., & Ma, T. (2022) · Advanced Materials · doi:10.1002/adma.202202508 · Cited by 294
Zu, D., Ying, Y., Wei, Q., Xiong, P., Ahmed, M. S., Lin, Z., Li, M. M., Li, M., Xu, Z., Chen, G., et al. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202405756 · Cited by 291
Metadata
- Authors
- Wang, X., Wang, X., Huang, J., Li, S., Meng, A., & Li, Z.
- Venue
- Nature Communications
- Published
- 2021-07-05
- Volume
- 12
- Issue
- 1
- Pages
- 4112-4112
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3133226951
- Cited by
- 1,099
- References
- 3
- FWCI
- 30.32
- Type
- journal article
- Language
- en
- Open access
- gold
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- Wang, X., Wang, X., Huang, J., Li, S., Meng, A., & Li, Z. (2021). Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution. Nature Communications. https://doi.org/10.1038/s41467-021-24511-z
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