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Alcohols electrooxidation coupled with H2 production at high current densities promoted by a cooperative catalyst
Open accessAbstract
Electrochemical alcohols oxidation offers a promising approach to produce valuable chemicals and facilitate coupled H 2 production. However, the corresponding current density is very low at moderate cell potential that substantially limits the overall productivity. Here we report the electrooxidation of benzyl alcohol coupled with H 2 production at high current density (540 mA cm−2 at 1.5 V vs. RHE) over a cooperative catalyst of Au nanoparticles supported on cobalt oxyhydroxide nanosheets (Au/CoOOH). The absolute current can further reach 4.8 A at 2.0 V in a more realistic two-electrode membrane-free flow electrolyzer. Experimental combined with theoretical results indicate that the benzyl alcohol can be enriched at Au/CoOOH interface and oxidized by the electrophilic oxygen species (OH*) generated on CoOOH, leading to higher activity than pure Au. Based on the finding that the catalyst can be reversibly oxidized/reduced at anodic potential/open circuit, we design an intermittent potential (IP) strategy for long-term alcohol electrooxidation that achieves high current density (>250 mA cm−2) over 24 h with promoted productivity and decreased energy consumption.
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Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Cited by
Chen, D., Ding, Y., Cao, X., Wang, L., Lee, H., Lin, G., Li, W., Ding, G., & Sun, L. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202309478 · Cited by 235
Circumventing Challenges: Design of Anodic Electrocatalysts for Hybrid Water Electrolysis Systems
Wang, H., Sun, M., Ren, J., & Yuan, Z. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203568 · Cited by 183
Gao, T., An, Q., Tang, X., Yue, Q., Zhang, Y., Li, B., Li, P., & Jin, Z. (2024) · Physical Chemistry Chemical Physics · doi:10.1039/d4cp01680g · Cited by 35
Metadata
- Authors
- Li, Z., Yan, Y., Xu, S.-M., Zhou, H., Xu, M., Ma, L., Shao, M., Kong, X., Wang, B., Zheng, L., & Duan, H.
- Venue
- Nature Communications
- Published
- 2022-01-10
- Volume
- 13
- Issue
- 1
- Pages
- 147-147
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4206376053
- Cited by
- 446
- References
- 2
- FWCI
- 16.61
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, Z., Yan, Y., Xu, S.-M., Zhou, H., Xu, M., Ma, L., Shao, M., Kong, X., Wang, B., Zheng, L., & Duan, H. (2022). Alcohols electrooxidation coupled with H2 production at high current densities promoted by a cooperative catalyst. Nature Communications. https://doi.org/10.1038/s41467-021-27806-3
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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