The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting
Open accessAbstract
Bismuth vanadate (BiVO 4) has been widely investigated as a photocatalyst or photoanode for solar water splitting, but its activity is hindered by inefficient cocatalysts and limited understanding of the underlying mechanism. Here we demonstrate significantly enhanced water oxidation on the particulate BiVO 4 photocatalyst via in situ facet-selective photodeposition of dual-cocatalysts that exist separately as metallic Ir nanoparticles and nanocomposite of FeOOH and CoOOH (denoted as FeCoO x), as revealed by advanced techniques. The mechanism of water oxidation promoted by the dual-cocatalysts is experimentally and theoretically unraveled, and mainly ascribed to the synergistic effect of the spatially separated dual-cocatalysts (Ir, FeCoO x) on both interface charge separation and surface catalysis. Combined with the H 2-evolving photocatalysts, we finally construct a Z-scheme overall water splitting system using [Fe(CN)6]3−/4− as the redox mediator, whose apparent quantum efficiency at 420 nm and solar-to-hydrogen conversion efficiency are optimized to be 12.3% and 0.6%, respectively.
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Cites
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Nanoporous BiVO 4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
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Self-citationPhotocatalyst releasing hydrogen from water
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Self-citationWang, Q., & Domen, K. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00201 · Cited by 2,809
Self-citationArtificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
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Homogeneously dispersed multimetal oxygen-evolving catalysts
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Cited by
Engineering β-ketoamine covalent organic frameworks for photocatalytic overall water splitting
Yang, Y., Chu, X., Zhang, H.-Y., Zhang, R., Liu, Y.-H., Zhang, F.-M., Lu, M., Yang, Z.-D., & Lan, Y.-Q. (2023) · Nature Communications · doi:10.1038/s41467-023-36338-x · Cited by 281
Self-citationTang, Y., Jia, X., Guo, Y., Geng, Z., Wang, C., Liu, L., Zhang, J., Guo, W., Tan, X., Yu, T., et al. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203827 · Cited by 55
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Metadata
- Authors
- Qi, Y., Zhang, J., Kong, Y., Zhao, Y., Chen, S., Li, D., Liu, W., Chen, Y., Xie, T., Cui, J., Li, C., Domen, K., & Zhang, F.
- Venue
- Nature Communications
- Published
- 2022-01-25
- Volume
- 13
- Issue
- 1
- Pages
- 484-484
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4210628397
- Cited by
- 429
- References
- 48
- FWCI
- 16.87
- Type
- journal article
- Language
- en
- Open access
- gold
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- Qi, Y., Zhang, J., Kong, Y., Zhao, Y., Chen, S., Li, D., Liu, W., Chen, Y., Xie, T., Cui, J., Li, C., Domen, K., & Zhang, F. (2022). Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting. Nature Communications. https://doi.org/10.1038/s41467-022-28146-6
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