Unlocking synergy in bimetallic catalysts by core–shell design

Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts

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Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO2 Catalysts

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Bimetallic Nanocrystals: Syntheses, Properties, and Applications

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Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis

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Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms

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Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene

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Platinum–cobalt bimetallic nanoparticles in hollow carbon nanospheres for hydrogenolysis of 5-hydroxymethylfurfural

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Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity

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Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit

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Palladium–platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction

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Atomic-scale determination of surface facets in gold nanorods

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Dynamic restructuring drives catalytic activity on nanoporous gold–silver alloy catalysts

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Bimetallic synergy in cobalt–palladium nanocatalysts for CO oxidation

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A review of the use of gold catalysts in selective hydrogenation reactions Lynsey McEwana

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Selective Hydrogenation of 1,3-Butadiene in the Presence of an Excess of Alkenes over Supported Bimetallic Gold−Palladium Catalysts

Hugon, A., Delannoy, L., Krafft, J., & Louis, C. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp100479b · Cited by 159 · see citing works

Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties

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Long-Range Segregation Phenomena in Shape-Selected Bimetallic Nanoparticles: Chemical State Effects

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Supported gold catalysts for selective hydrogenation of 1,3-butadiene in the presence of an excess of alkenes

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Synthesis of Colloidal Pd/Au Dilute Alloy Nanocrystals and Their Potential for Selective Catalytic Oxidations.

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Pd–Au single-crystal surfaces: Segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene

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Electronic properties of supported Pd aggregates in relation with their reactivity for 1,3-butadiene hydrogenation

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Hydrogen Adsorption and Absorption with Pd–Au Bimetallic Surfaces

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From Pd nanoparticles to single crystals: 1,3-butadiene hydrogenation on well-defined model catalysts

Silvestre‐Albero, J., Rupprechter, G., & Freund, H. (2005) · Chemical Communications · doi:10.1039/b513030a · Cited by 80 · see citing works

Tuning the Electrocatalytic Oxygen Reduction Reaction Activity of Pt–Co Nanocrystals by Cobalt Concentration with Atomic-Scale Understanding

Lee, J. D., Jishkariani, D., Zhao, Y., Najmr, S., Rosen, D. J., Kikkawa, J. M., Stach, E. A., & Murray, C. B. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b06346 · Cited by 72 · see citing works

Dilute Pd/Au Alloy Nanoparticles Embedded in Colloid-Templated Porous SiO 2 : Stable Au-Based Oxidation Catalysts

Luneau, M., Shirman, T., Filie, A., Timoshenko, J., Chen, W., Trimpalis, A., Flytzani‐Stephanopoulos, M., Kaxiras, E., Frenkel, A. I., Aizenberg, J., et al. (2019) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b01779 · Cited by 71 · see citing works

Superior Stability of Au/SiO2 Compared to Au/TiO2 Catalysts for the Selective Hydrogenation of Butadiene

Masoud, N., Delannoy, L., Schaink, H., van der Eerden, A. V. D., de Rijk, J. W., Silva, T. A. G., Banerjee, D., Meeldijk, J., de Jong, K. D., Louis, C., et al. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01424 · Cited by 59 · see citing works

Oxidative Etching and Metal Overgrowth of Gold Nanorods within Mesoporous Silica Shells

Deng, T., van der Hoeven, J. E. S., Yalcin, A. O., Zandbergen, H. W., van Huis, M. A., & van Blaaderen, A. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b03749 · Cited by 52 · see citing works

Detecting the Genesis of a High-Performance Carbon-Supported Pd Sulfide Nanophase and Its Evolution in the Hydrogenation of Butadiene

Bachiller‐Baeza, B., Iglesias‐Juez, A., Castillejos, E., Guerrero-Ruiz, A. R., Michiel, M. D., Fernández–García, M., & Rodríguez-Ramos, I. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00896 · Cited by 48 · see citing works

In Situ Observation of Atomic Redistribution in Alloying Gold–Silver Nanorods

van der Hoeven, J. E. S., Welling, T. A. J., Silva, T. A. G., van den Reijen, J. E., Fontaine, C. L., Carrier, X., Louis, C., van Blaaderen, A., & de Jongh, P. E. (2018) · ACS Nano · doi:10.1021/acsnano.8b03978 · Cited by 47 · see citing works

The Crucial Role of the Support in the Transformations of Bimetallic Nanoparticles and Catalytic Performance

Destro, P., Kokumai, T. M., Scarpellini, A., Pasquale, L., Manna, L., Colombo, M., & Zanchet, D. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03685 · Cited by 44 · see citing works

Probing the Electronic Structure of Heterogeneous Metal Interfaces by Transition Metal Shelled Gold Nanoparticle-Enhanced Raman Spectroscopy

Zhang, Y., Li, S., Duan, S., Lu, B., Yang, J., Panneerselvam, R., Li, C., Fang, P., Zhou, Z., Phillips, D. L., et al. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b01879 · Cited by 40 · see citing works

The epitaxial growth of Pd electrodeposition on Au(100) studied by LEED and RHEED

Pinheiro, A. L. N., Zei, M. S., Luo, M.-F., & Ertl, G. (2005) · Surface Science · doi:10.1016/j.susc.2005.10.057 · Cited by 39 · see citing works

Silica‐Supported Au–Ag Catalysts for the Selective Hydrogenation of Butadiene

Masoud, N., Delannoy, L., Calers, C., Gallet, J., Bournel, F., de Jong, K. P., Louis, C., & de Jongh, P. E. (2017) · ChemCatChem · doi:10.1002/cctc.201700127 · Cited by 29 · see citing works

Strained Pd films, by epitaxial growth on Au(), to control catalytic properties

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Bimetallic Sites for Catalysis: From Binuclear Metal Sites to Bimetallic Nanoclusters and Nanoparticles

Liu, L., & Corma, A. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00733 · Cited by 696 · see citing works

Designing Sites in Heterogeneous Catalysis: Are We Reaching Selectivities Competitive With Those of Homogeneous Catalysts?

Zaera, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00905 · Cited by 434 · see citing works

Catalysis of Alloys: Classification, Principles, and Design for a Variety of Materials and Reactions

Nakaya, Y., & Furukawa, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00356 · Cited by 419 · see citing works

Materials-Driven Soft Wearable Bioelectronics for Connected Healthcare

Gong, S. P., Yan, L., Yin, J., Levin, A., & Cheng, W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00502 · Cited by 424 · see citing works

Liquid‐Metal‐Assisted Programmed Galvanic Engineering of Core–shell Nanohybrids for Microwave Absorption

Zhao, B., Du, Y., Lv, H., Yan, Z., Jian, H., Chen, G., Wu, Y., Fan, B., Zhang, J., Wu, L., et al. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202302172 · Cited by 255 · see citing works

Synthesis of core/shell nanocrystals with ordered intermetallic single-atom alloy layers for nitrate electroreduction to ammonia

Gao, Q., Yao, B., Pillai, H. S., Zang, W., Han, X., Liu, Y., Yu, S., Yan, Z., Min, B., Zhang, S., et al. (2023) · Nature Synthesis · doi:10.1038/s44160-023-00258-x · Cited by 252 · see citing works

Preparation of Au@Pd Core–Shell Nanorods with fcc-2H-fcc Heterophase for Highly Efficient Electrocatalytic Alcohol Oxidation

Zhou, X., Ma, Y., Ge, Y., Zhu, S., Cui, Y., Chen, B., Liao, L., Yun, Q., He, Z., Long, H., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c11313 · Cited by 216 · see citing works

Coordination environment of active sites and their effect on catalytic performance of heterogeneous catalysts

Wang, C., Wang, Z., Mao, S., Chen, Z., & Wang, Y. (2022) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(21)63924-4 · Cited by 144 · see citing works

Origin of hetero-nuclear Au-Co dual atoms for efficient acidic oxygen reduction

Kong, F., Si, R., Chen, N., Wang, Q., Li, J., Yin, G., Gu, M., Wang, J., Liu, L., & Sun, X. A. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120782 · Cited by 95 · see citing works

Conjugated dual size effect of core-shell particles synergizes bimetallic catalysis

Zhang, X., Sun, Z., Jin, R. M., Zhu, C., Zhao, C., Lin, Y., Guan, Q., Cao, L., Wang, H., Li, S., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-36147-2 · Cited by 94 · see citing works

Metal Phosphide: An Atypical Catalytic Site

Liu, B., Lan, X., Zhong, Q., & Wang, T. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c05160 · Cited by 89 · see citing works

Preparation of fcc ‐2H‐ fcc Heterophase Pd@Ir Nanostructures for High‐Performance Electrochemical Hydrogen Evolution

Ge, Y., Wang, X., Chen, B., Huang, Z., Shi, Z., Huang, B., Liu, J., Wang, G., Chen, Y., Li, L., et al. (2021) · Advanced Materials · doi:10.1002/adma.202107399 · Cited by 83 · see citing works

Controllable Constructing Janus Homologous Heterostructures of Transition Metal Alloys/Sulfides for Efficient Oxygen Electrocatalysis

Lu, Q., Wu, H., Zheng, X., Cao, Y., Li, J., Wang, Y., Wang, H., Zhi, C., Deng, Y., Han, X., et al. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202202215 · Cited by 83 · see citing works

A doping element improving the properties of catalysis: in situ Raman spectroscopy insights into Mn-doped NiMn layered double hydroxide for the urea oxidation reaction

Yang, X., Zhang, H. M., Xu, W. M., Yu, B., Liu, Y., & Wu, Z. (2022) · Catalysis Science & Technology · doi:10.1039/d2cy00308b · Cited by 78 · see citing works

Rapid Screening of Bimetallic Electrocatalysts Using Single Nanoparticle Collision Electrochemistry

Li, H., Zhang, X., Sun, Z., & Ma, W. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c05299 · Cited by 76 · see citing works

Structural Reconstruction of Catalysts in Electroreduction Reaction: Identifying, Understanding, and Manipulating

Wang, W., Duan, J., Liu, Y., & Zhai, T. (2022) · Advanced Materials · doi:10.1002/adma.202110699 · Cited by 70 · see citing works

Activating ruthenium dioxide via compressive strain achieving efficient multifunctional electrocatalysis for Zn‐air batteries and overall water splitting

Qiu, Y., Rao, Y., Zheng, Y., Hu, H., Zhang, W., & Guo, X. (2022) · InfoMat · doi:10.1002/inf2.12326 · Cited by 69 · see citing works

Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production

Fan, Z.-L., Liao, F., Ji, Y.-J., Liu, Y., Huang, H., Wang, D., Yin, K., Yang, H., Ma, M.-J., Zhu, W.-X., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-33512-5 · Cited by 45 · see citing works

Stabilizing supported atom-precise low-nuclearity platinum cluster catalysts by nanoscale confinement

Chen, Y., Zhao, J., Zhao, X., Wu, D., Zhang, N., Du, J., Zeng, J., Li, X., Salmerón, M., Liu, J., et al. (2025) · Nature Chemical Engineering · doi:10.1038/s44286-024-00162-x · Cited by 65 · see citing works

Silica‐Coated Gold Nanorod Supraparticles: A Tunable Platform for Surface Enhanced Raman Spectroscopy

van der Hoeven, J. E. S., Gurunarayanan, H., Bransen, M., de Winter, D. A. M., de Jongh, P. E., & van Blaaderen, A. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202200148 · Cited by 56 · see citing works

Regioselective epitaxial growth of metallic heterostructures

Huang, X., Feng, J., Xu, B., Xu, B., Hao, M., Liu, X., Wen, Y., Su, D., Li, Y., Li, Y., et al. (2024) · Nature Nanotechnology · doi:10.1038/s41565-024-01696-0 · Cited by 55 · see citing works

Pioneering Built‐In Interfacial Electric Field for Enhanced Anion Exchange Membrane Water Electrolysis

Huang, H., Xu, L., Zuo, S., Ren, Y., Song, L., Zou, C., Wang, X. M., Martínez, J. R., Huang, K., & Zhang, H. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202414647 · Cited by 55 · see citing works

Structural Regulation of Au‐Pt Bimetallic Aerogels for Catalyzing the Glucose Cascade Reaction

Wang, C., Wang, L., Nallathambi, V., Liu, Y., Kresse, J., Hübner, R., Reichenberger, S., Gault, B., Zhan, J., Eychmüller, A., et al. (2024) · Advanced Materials · doi:10.1002/adma.202405200 · Cited by 53 · see citing works

Layered double hydroxides-based metal nanocatalysts: Confinement engineering, microenvironment effect and applications in catalytic conversion of biomass

Wu, J., Xie, Y., Li, Y., Jin, M., Liu, L., Pan, G., Wang, C., & Li, F. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2023.215437 · Cited by 49 · see citing works

Strategies to improve hydrogen activation on gold catalysts

Dimitratos, N., Vilé, G., Albonetti, S., Cavani, F., Fiorio, J., López, N., Rossi, L. M., & Wojcieszak, R. (2024) · Nature Reviews Chemistry · doi:10.1038/s41570-024-00578-2 · Cited by 39 · see citing works

Stabilization of Exposed Metal Nanocrystals in High‐Temperature Heterogeneous Catalysis

Zhu, Z., Feng, K. M., Li, C., Tang, R., Xiao, M., Song, R., Yang, D., Yan, B., & He, L. (2021) · Advanced Materials · doi:10.1002/adma.202108727 · Cited by 48 · see citing works

Microwave discharge for rapid introduction of bimetallic-synergistic configuration to conductive catecholate toward long-term supercapacitor

Jiang, H., Xian, J., Hu, R. H., Mi, S., Wei, L., Fang, G., Wu, Z., Xu, S., Fan, M., Liu, K., et al. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.140804 · Cited by 42 · see citing works

Bimetal anchoring porous MXene nanosheets for driving tandem catalytic high‐efficiency electrochemical nitrate reduction

Guo, R., Cui, Z., Yu, T., Li, J., Peng, W., & Liu, J. (2024) · AIChE Journal · doi:10.1002/aic.18628 · Cited by 42 · see citing works

AuPt bimetallic nanoalloys supported on SBA-15: A superior catalyst for quinoline selective hydrogenation in water

Zhao, J., Yuan, H., Yang, G., Liu, Y., Qin, X., Chen, Z., Cheong, W.-C. M., Zhou, L., & Fang, S. (2021) · Nano Research · doi:10.1007/s12274-021-3732-1 · Cited by 41 · see citing works

Synergies of Ru/Co nanoparticles and Co single atoms active sites toward efficient electrocatalysis of oxygen reduction reaction for Zn-Air battery

Luo, X., Zhao, S., Luo, Z., Li, S., Zhao, X. D., Fang, Q., Wei, X., Wang, H., Wang, C., Zhu, Z., et al. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.142184 · Cited by 40 · see citing works

Probing the atomically diffuse interfaces in Pd@Pt core-shell nanoparticles in three dimensions

Li, Z., Xie, Z., Zhang, Y., Mu, X., Xie, J., Yin, H., Zhang, Y., Ophus, C., & Zhou, J. (2023) · Nature Communications · doi:10.1038/s41467-023-38536-z · Cited by 40 · see citing works

Selective hydrogenation of glucose to sorbitol with tannic acid-based porous carbon sphere supported Ni–Ru bimetallic catalysts

Xi, R., Tang, Y., Smith, R. L., Liu, X., Liu, L., & Qi, X. (2022) · Green Energy & Environment · doi:10.1016/j.gee.2022.04.003 · Cited by 40 · see citing works

Simultaneous production of hydrogen and carbon nanotubes from biogas over mono- and bimetallic catalyst

Rattanaamonkulchai, R., Kludpantanapan, T., Srifa, A., Koo-amornpattana, W., Chaiwat, W., Sakdaronnarong, C. K., Charinpanitkul, T., Assabumrungrat, S., Wongsakulphasatch, S., Show, P.-L., et al. (2022) · Journal of environmental chemical engineering · doi:10.1016/j.jece.2022.107910 · Cited by 39 · see citing works

Supported Cu Nanoparticles as Selective and Stable Catalysts for the Gas Phase Hydrogenation of 1,3-Butadiene in Alkene-Rich Feeds

Totarella, G., Beerthuis, R., Masoud, N., Louis, C., Delannoy, L., & de Jongh, P. E. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c08077 · Cited by 38 · see citing works

Unlocking the catalytic potential of heterogeneous nonprecious metals for selective hydrogenation reactions

Gong, W., Ma, J., Chen, G., Dai, Y., Long, R., Zhao, H., & Xiong, Y. (2024) · Chemical Society Reviews · doi:10.1039/d4cs01005a · Cited by 37 · see citing works

Design strategies and structure-performance relationships of heterogeneous catalysts for selective hydrogenation of 1,3-butadiene

Wang, M., Wang, Y., Mou, X., Lin, R., & Ding, Y. (2022) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(21)63942-6 · Cited by 34 · see citing works

Influence of particle size in Pd-catalysed selective hydrogenation of 1,3-butadiene

Corstius, O. E. B., van der Hoeven, J. E. S., Sunley, G. J., & de Jongh, P. E. (2023) · Journal of Catalysis · doi:10.1016/j.jcat.2023.115103 · Cited by 33 · see citing works

Revealing Structural Evolution of Nickel Phosphide-Iron Oxide Core–Shell Nanocatalysts in Alkaline Medium for the Oxygen Evolution Reaction

Manso, R. H., Hong, J., Wang, W., Acharya, P., Hoffman, A. S., Tong, X., Wang, F., Greenlee, L. F., Zhu, Y., Bare, S. R., et al. (2024) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c00379 · Cited by 33 · see citing works

Visualizing the Birth and Monitoring the Life of a Bimetallic Methanation Catalyst

Yan, X., Cao, M., Li, S., Duchesne, P. N., Sun, W. L., Mao, C., Song, R., Lu, Z., Chen, X., Qian, W., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c07668 · Cited by 32 · see citing works

Insights into mechanism of Fe-dominated active sites via phosphorus bridging in Fe-Ni bimetal single atom photocatalysts

Zhan, R., Zhou, Y., Liu, C., Wang, X., Sun, X., Zhu, Y., & Niu, J. (2022) · Separation and Purification Technology · doi:10.1016/j.seppur.2022.120443 · Cited by 32 · see citing works

Achieving “True” Selective Hydrogenation by CO Treatment of the Pt/TiO2 Catalyst

Zhang, F., Hong, F., Qin, X., Du, X., Jiang, X., Li, Y., Guo, H., Liu, P., Cui, W., Min, X., et al. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c04699 · Cited by 30 · see citing works

E-waste derived CuAu bimetallic catalysts supported on carbon cloth enabling effective degradation of bisphenol A via an electro-Fenton process

Ye, M., Zhang, C., Liu, Z., Li, H., Fu, Z., Zhang, H., Wang, G., & Zhang, Y. (2022) · Separation and Purification Technology · doi:10.1016/j.seppur.2022.122507 · Cited by 30 · see citing works

Pt–Co bimetals supported on UiO-66 as efficient and stable catalysts for the catalytic oxidation of various volatile organic compounds

Xu, Z., Li, J., Wang, X., Wang, T., Li, D., & Ao, Z. (2023) · Materials Today Chemistry · doi:10.1016/j.mtchem.2023.101403 · Cited by 30 · see citing works

Propene epoxidation with molecular oxygen: Advancements from nanoparticle to single‐atom catalysts

He, Q., Lin, D., Yin, D., Yang, C., Chen, D., & Feng, X. (2024) · Smart Molecules · doi:10.1002/smo.20240025 · Cited by 29 · see citing works

Precise Design of Atomically Dispersed Fe, Pt Dinuclear Catalysts and Their Synergistic Application for Tumor Catalytic Therapy

Wang, S., Hu, Z., Wei, Q., Cui, P., Zhang, H., Tang, W., Sun, Y., Duan, H., Dai, Z., Liu, Q., et al. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c01683 · Cited by 29 · see citing works

Revealing synergetic structural activation of a CuAu surface during water–gas shift reaction

Dong, Z., Nian, Y., Liu, H., Chen, J., Wang, Y., Wang, S., Xu, J. M., Han, Y., & Luo, L. (2022) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.2120088119 · Cited by 27 · see citing works

Review of chemical looping process for carbonaceous feedstock Conversion: Rational design of oxygen carriers

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Synergistic effects boost electrocatalytic reduction of bromate on supported bimetallic Ru-Cu catalyst

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