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Chemical stability of hydrogen boride nanosheets in water
Abstract
Boron-based two-dimensional materials are of interest for use in electronic devices and catalytic applications, for which it is important that they are chemically stable. Here, we explore the chemical stability of hydrogen boride nanosheets in water. Experiments reveal that mixing hydrogen boride and water produces negligible amounts of hydrogen, suggesting that hydrolysis does not occur and that hydrogen boride is stable in water, which is in contrast to most boron hydride materials. First-principles calculations reveal that the sheets interact weakly with water even in the presence of defects and that negatively charged boron prevents the onset of hydrolysis. We conclude that the charge state of boron and the covalent boron-boron bond network are responsible for the chemical and structural stability. On the other hand, we found that proton exchange with hydrogen boride nanosheets does occur in water, indicating that they become acidic in the presence of water.
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Research works printed but not linked: 1
- Rojas, K. I. M. et al. Chemical stability of hydrogen boride nanosheets in water. Materials Cloud Archive 2021.87 https://doi.org/10.24435/materialscloud:40-28 (2021). · DOI
Metadata
- Authors
- Rojas, K. I. M., Cuong, N. T., Nishino, H., Ishibiki, R., Ito, S.-I., Miyauchi, M., Fujimoto, Y., Tominaka, S., Okada, S., Hosono, H., Arboleda, N. B., Kondo, T., Morikawa, Y., & Hamada, I.
- Venue
- Communications Materials
- Published
- 2021-07-23
- Volume
- 2
- Issue
- 1
- ISSN
- 2662-4443
- Cited by
- 40
- References
- 51
- Language
- en
- Licence
- creativecommons.org/licenses/by/4.0 (tdm)
- creativecommons.org/licenses/by/4.0 (vor)
- Funders
- DOST | National Research Council of the Philippines
- MEXT | Japan Society for the Promotion of Science (JP18K18989, JP19H02551, JP19H05046, JP21H00015, JPMXP0112101001, JP20H02569, JP18H05519)
- Kumagai Foundation for Science and Technology
- Ogasawara Foundation for the Promotion of Science and Engineering
- - Samco foundations for the Promotion of Science & Engineering - MHI Innovation Accelerator LLC
- The Tokyo Electron Ltd
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