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Oxygen vacancies promoting photoelectrochemical performance of In2O3 nanocubes

Open access
Gan, Jiayong, Lu, Xihong, Wu, Jingheng, Xie, Shilei, Zhai, Teng, Yu, Minghao, Zhang, Zishou, Mao, Yanchao, Wang, Shing Chi Ian, Shen, Yong, Tong, Yexiang·2013·Scientific Reports

Abstract

This work reports a facile method for preparing the new photoactive In(2)O(3) films as well as their implementation in photoelectrochemical (PEC) application. We firstly investigated the relationship between oxygen vacancies (V(O)) and PEC performance and revealed a rule between them. We found that the optimized In(2)O(3-n) sample yielded a photocurrent density up to 3.83 mA/cm(2) in 1 M Na(2)SO(4) solution under the solar illumination. It also gave efficiency as high as 75% over 400 nm in the incident-photon-to-current-conversion efficiency (IPCE) spectrum, which is the best value for an In(2)O(3) photoanode reported. Moreover, the PEC performance of these films is enhanced as the V(O) increased and then decreased with further increasing V(O). This two-side effect means V(O) can favor the photoelectron activation, or act as recombination centers to prohibit the generation of photocurrent. Making highly photoactive In(2)O(3) nanostructures in this work will open up new opportunities in various areas.

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Metadata

Authors
Gan, J., Lu, X., Wu, J., Xie, S., Zhai, T., Yu, M., Zhang, Z., Mao, Y., Wang, S. C. I., Shen, Y., & Tong, Y.
Venue
Scientific Reports
Published
2013-01-04
Volume
3
Issue
1
Pages
1021-1021
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2063010248
Cited by
558
References
27
FWCI
14.43
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Oxygen vacancies promoting photoelectrochemical performance of In2O3 nanocubes. https://app.cochat.ai/papers/10.1038/srep01021
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Gan, J., Lu, X., Wu, J., Xie, S., Zhai, T., Yu, M., Zhang, Z., Mao, Y., Wang, S. C. I., Shen, Y., & Tong, Y. (2013). Oxygen vacancies promoting photoelectrochemical performance of In2O3 nanocubes. Scientific Reports. https://doi.org/10.1038/srep01021

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