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Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors

Open access
Tao, Ying, Xie, Xiaoying, Lv, Wei, Tang, Dai-Ming, Kong, Debin, Huang, Zhenghong, Nishihara, Hirotomo, Ishii, Takafumi, Li, Baohua, Golberg, Dmitri, Kang, Feiyu, Kyotani, Takashi, Yang, Quan-Hong·2013·Scientific Reports

Abstract

A small volumetric capacitance resulting from a low packing density is one of the major limitations for novel nanocarbons finding real applications in commercial electrochemical energy storage devices. Here we report a carbon with a density of 1.58 g cm(-3), 70% of the density of graphite, constructed of compactly interlinked graphene nanosheets, which is produced by an evaporation-induced drying of a graphene hydrogel. Such a carbon balances two seemingly incompatible characteristics: a porous microstructure and a high density, and therefore has a volumetric capacitance for electrochemical capacitors (ECs) up to 376 F cm(-3), which is the highest value so far reported for carbon materials in an aqueous electrolyte. More promising, the carbon is conductive and moldable, and thus could be used directly as a well-shaped electrode sheet for the assembly of a supercapacitor device free of any additives, resulting in device-level high energy density ECs.

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Crossref · 10.1038/srep02975

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Metadata

Authors
Tao, Y., Xie, X., Lv, W., Tang, D.-M., Kong, D., Huang, Z., Nishihara, H., Ishii, T., Li, B., Golberg, D., Kang, F., Kyotani, T., & Yang, Q.-H.
Venue
Scientific Reports
Published
2013-10-17
Volume
3
Issue
1
Pages
2975-2975
ISSN
2045-2322 (ISSN-L)
OpenAlex
W2053848721
Cited by
628
References
4
FWCI
18.25
Type
journal article
Language
en
Open access
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CoChat. (2026). Citation check: Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors. https://app.cochat.ai/papers/10.1038/srep02975
The paper
Tao, Y., Xie, X., Lv, W., Tang, D.-M., Kong, D., Huang, Z., Nishihara, H., Ishii, T., Li, B., Golberg, D., Kang, F., Kyotani, T., & Yang, Q.-H. (2013). Towards ultrahigh volumetric capacitance: graphene derived highly dense but porous carbons for supercapacitors. Scientific Reports. https://doi.org/10.1038/srep02975

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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