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Role of Peroxide Ions in Formation of Graphene Nanosheets by Electrochemical Exfoliation of Graphite
Open accessAbstract
This study demonstrates a facile, mild and environmentally-friendly sustainable (soft processing) approach for the efficient electrochemical exfoliation of graphite using a sodium hydroxide/hydrogen peroxide/water (NaOH/H2O2/H2O) system that can produce high-quality, anodic few-layer graphene nanosheets in 95% yield at ambient reaction conditions. The control experiment conducted using NaOH/H2O revealed the crucial role of H2O2 in the exfoliation of graphite. A possible exfoliation mechanism is proposed. The reaction of H2O2 with hydroxyl ions (HO(-)) leads to the formation of highly nucleophilic peroxide ions (O2(2-)), which play a crucial role in the exfoliation of graphite via electrochemical-potential-assisted intercalation and strong expansion of graphite sheets.
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Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Cited by
Kumar, R., Sahoo, S., Joanni, E., Singh, R. K., Tan, W. K., Kar, K. K., & Matsuda, A. (2019) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2019.100786 · Cited by 554
Graphene and its electrochemistry – an update
Ambrosi, A., Chua, C. K., Latiff, N. M., Loo, A. H., Wong, C. H. A., Eng, A. Y. S., Bonanni, A., & Pumera, M. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00136j · Cited by 469
Surface Modification of 2D Photocatalysts for Solar Energy Conversion
Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
Electrochemical exfoliation of graphite and production of functional graphene
Yu, P., Lowe, S. E., Simon, G. P., & Zhong, Y. L. (2015) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2015.10.007 · Cited by 361
New‐Generation Graphene from Electrochemical Approaches: Production and Applications
Yang, S., Lohe, M. R., Müllen, K., & Feng, X. (2016) · Advanced Materials · doi:10.1002/adma.201505326 · Cited by 313
Metadata
- Authors
- Rao, K. S., Senthilnathan, J., Liu, Y.-F., & Yoshimura, M.
- Venue
- Scientific Reports
- Published
- 2014-02-28
- Volume
- 4
- Issue
- 1
- Pages
- 4237-4237
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2081029776
- Cited by
- 197
- References
- 1
- FWCI
- 6.55
- Type
- journal article
- Language
- en
- Open access
- gold
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- Rao, K. S., Senthilnathan, J., Liu, Y.-F., & Yoshimura, M. (2014). Role of Peroxide Ions in Formation of Graphene Nanosheets by Electrochemical Exfoliation of Graphite. Scientific Reports. https://doi.org/10.1038/srep04237
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