The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide
Open accessAbstract
Zn-ion batteries are emerging energy storage systems eligible for large-scale applications, such as electric vehicles. These batteries consist of totally environmentally-benign electrode materials and potentially manufactured very economically. Although Zn/α-MnO2 systems produce high energy densities of 225 Wh kg(-1), larger than those of conventional Mg-ion batteries, they show significant capacity fading during long-term cycling and suffer from poor performance at high current rates. To solve these problems, the concrete reaction mechanism between α-MnO2 and zinc ions that occur on the cathode must be elucidated. Here, we report the intercalation mechanism of zinc ions into α-MnO2 during discharge, which involves a reversible phase transition of MnO2 from tunneled to layered polymorphs by electrochemical reactions. This transition is initiated by the dissolution of manganese from α-MnO2 during discharge process to form layered Zn-birnessite. The original tunneled structure is recovered by the incorporation of manganese ions back into the layers of Zn-birnessite during charge process.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Manganese oxide minerals: Crystal structures and economic and environmental significance
Post, J. E. (1999) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.96.7.3447 · Cited by 1,854
Cited by
Scientific Challenges for the Implementation of Zn-Ion Batteries
Blanc, L. E., Kundu, D., & Nazar, L. F. (2020) · Joule · doi:10.1016/j.joule.2020.03.002 · Cited by 2,113
Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3
Li, G., Yang, Z., Jiang, Y., Jin, C., Huang, W., Ding, X., & Huang, Y. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.051 · Cited by 734
Nam, K. W., Park, S. S., dos Reis, R., Dravid, V. P., Kim, H., Mirkin, C. A., & Stoddart, J. F. (2019) · Nature Communications · doi:10.1038/s41467-019-12857-4 · Cited by 688
Li, H., Liu, Z., Liang, G., Huang, Y., Huang, Y., Zhu, M., Pei, Z., Xue, Q., Tang, Z., Wang, Y., et al. (2018) · ACS Nano · doi:10.1021/acsnano.7b09003 · Cited by 587
Metadata
- Authors
- Lee, B., Yoon, C. S., Lee, H. R., Chung, K. Y., Cho, B. W., & Oh, S. H.
- Venue
- Scientific Reports
- Published
- 2014-08-14
- Volume
- 4
- Issue
- 1
- Pages
- 6066-6066
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2041439158
- Cited by
- 357
- References
- 1
- FWCI
- 6.72
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide. https://app.cochat.ai/papers/10.1038/srep06066
- The paper
- Lee, B., Yoon, C. S., Lee, H. R., Chung, K. Y., Cho, B. W., & Oh, S. H. (2014). Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide. Scientific Reports. https://doi.org/10.1038/srep06066
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
