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Tungsten Ditelluride: a layered semimetal
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Tungsten ditelluride (WTe 2) is a transition metal dichalcogenide (TMD) with physical and electronic properties that make it attractive for a variety of electronic applications. Although WTe 2 has been studied for decades, its structure and electronic properties have only recently been correctly described. We experimentally and theoretically investigate the structure, dynamics and electronic properties of WTe 2 and verify that WTe 2 has its minimum energy configuration in a distorted 1T structure (Td structure), which results in metallic-like transport. Our findings unambiguously confirm the metallic nature of WTe 2, introduce new information about the Raman modes of Td-WTe 2 and demonstrate that Td-WTe 2 is readily oxidized via environmental exposure. Finally, these findings confirm that, in its thermodynamically favored Td form, the utilization of WTe 2 in electronic device architectures such as field effect transistors may need to be reevaluated.
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Metadata
- Authors
- Lee, C.-H., Silva, E. C., Calderin, L., Nguyen, M. A. T., Hollander, M. J., Bersch, B., Mallouk, T. E., & Robinson, J. A.
- Venue
- Scientific Reports
- Published
- 2015-06-12
- Volume
- 5
- Issue
- 1
- Pages
- 10013-10013
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2267636025
- Cited by
- 264
- References
- 42
- FWCI
- 9.33
- Type
- journal article
- Language
- en
- Open access
- gold
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