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Dielectric parameters relevant to microwave dielectric heating
Abstract
Microwave dielectric heating is rapidly becoming an established procedure in synthetic chemistry. This review summarises the basic theory underlying microwave dielectric heating and collates the dielectric data for a wide range of organic solvents which are commmonly used in microwave syntheses. The loss tangents of the solvents, which may be related to the ability of the solvent to absorb energy in a microwave cavity, depend on the relaxation times of the molecules. These relaxation times depend critically on the nature of the functional groups and the volume of the molecule. Functional groups capable of hydrogenbonding have a particularly strong influence on the relaxation times. The relaxation times of solvents decrease as the temperature of the solvent is increased. Loss tangent data at different microwave frequencies are also presented and discussed.
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Cites
Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics
Cole, K. S., & Cole, R. H. (1941) · The Journal of Chemical Physics · doi:10.1063/1.1750906 · Cited by 10,152
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Synthesis of Inorganic Solids Using Microwaves
Rao, K. J., Vaidhyanathan, B., Ganguli, M., & Ramakrishnan, P. A. (1999) · Chemistry of Materials · doi:10.1021/cm9803859 · Cited by 803
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Metadata
- Authors
- Gabriel, C., Gabriel, S., H. Grant, E., H. Grant, E., S. J. Halstead, B., & Michael P. Mingos, D.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 1998
- Volume
- 27
- Issue
- 3
- Pages
- 213
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2170424911
- Cited by
- 1,401
- References
- 1
- FWCI
- 1.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gabriel, C., Gabriel, S., H. Grant, E., H. Grant, E., S. J. Halstead, B., & Michael P. Mingos, D. (1998). Dielectric parameters relevant to microwave dielectric heating. Chemical Society Reviews. https://doi.org/10.1039/a827213z
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
