The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Influence of the boundaries in the impedance of porous film electrodes
Abstract
This paper presents an enhanced model for the impedance of porous film electrodes. The impedance of a transmission line with two transport channels, a crosswise element and arbitrary terminal loads is solved analytically. The local impedances at the boundaries represent a frequency-dependent response of the blocking of ionic and electronic charge carriers at the two faces of the electrode region. A general expression is found that contains, as particular cases, a number of models of impedance for porous electrodes used in the literature. Some examples of the generalised transmission line illustrate the use of the model in the interpretation of experimental data. First, a polarisable electrode showing low-frequency dispersion of the constant phase element (CPE) type is analysed, and diagnosis criteria are derived to recognise whether the dispersion is caused by the boundary or the inner surface. Secondly, the manifestation in the impedance of the failure of a porous electrode due to direct charge transfer between the substrate and a redox couple in solution is investigated.
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Cites
van de Lagemaat, J., Park, N.-G., & Frank, A. J. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993172v · Cited by 788
Impedance of constant phase element (CPE)-blocked diffusion in film electrodes
Bisquert, J., García-Belmonte, G., Bueno, P. R., Longo, E., & Bulhões, L. O. S. (1998) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(98)00115-6 · Cited by 463
Self-citationBisquert, J., Garcia-Belmonte, G., Fabregat-Santiago, F., Ferriols, N. S., Bogdanoff, P., & Pereira, E. C. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993148h · Cited by 361
Self-citationImpedance studies of porous electrodes
Raistrick, I. D. (1990) · Electrochimica Acta · doi:10.1016/0013-4686(90)80013-e · Cited by 255
Cited by
Electrochemical Impedance Spectroscopy─A Tutorial
Lazanas, A. C., & Prodromidis, M. I. (2023) · ACS Measurement Science Au · doi:10.1021/acsmeasuresciau.2c00070 · Cited by 3,123
Theory of the Impedance of Electron Diffusion and Recombination in a Thin Layer
Bisquert, J. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp011941g · Cited by 1,361
Self-citationHuang, J. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.05.136 · Cited by 469
Da Silva, L. M., Cesar, R., Moreira, C. M. R., Santos, J. H. M., De Souza, L. G., Pires, B. M., Vicentini, R., Nunes, W., & Zanin, H. (2020) · Energy Storage Materials · doi:10.1016/j.ensm.2019.12.015 · Cited by 357
Guerrero, A., Bisquert, J., & Garcia-Belmonte, G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00214 · Cited by 339
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Metadata
- Authors
- Bisquert, J.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2000
- Volume
- 2
- Issue
- 18
- Pages
- 4185-4192
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2111886042
- Cited by
- 342
- References
- 4
- FWCI
- 3.86
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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