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Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol
Abstract
Supercritical carbon dioxide is efficiently converted to dimethyl carbonate (DMC) via the reaction with methanol in the presence of a catalytic amount of dialkyltin oxide or its derivatives. The removal of water is the key to accomplishing the high conversion by shifting the equilibrium to dimethyl carbonate. Dehydration is successfully carried out by circulating the reaction mixture through a dehydrating tube packed with molecular sieve 3A. Under the effective dehydration conditions, the DMC yield is almost linearly dependent on the reaction time, catalyst amount, methanol concentration, and CO2 pressure.
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Citations
Cited by
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Self-citationMultiscale Studies on Ionic Liquids
Dong, K., Liu, X., Dong, H., Zhang, X., & Zhang, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00776 · Cited by 773
Carbon capture and utilization technologies: a literature review and recent advances
Baena-Moreno, F. M., Rodríguez-Galán, M., Vega, F., Alonso-Fariñas, B., Vilches Arenas, L. F., & Navarrete, B. (2019) · Energy Sources, Part A: Recovery, Utilization, and Environmental Effects · doi:10.1080/15567036.2018.1548518 · Cited by 351
Metadata
- Authors
- Choi, J.-C., He, L.-N., Yasuda, H., & Sakakura, T.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002-04-16
- Volume
- 4
- Issue
- 3
- Pages
- 230-234
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2019716301
- Cited by
- 250
- References
- 0
- FWCI
- 3.94
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol. https://app.cochat.ai/papers/10.1039/b200623p
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- Choi, J.-C., He, L.-N., Yasuda, H., & Sakakura, T. (2002). Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol. Green Chemistry. https://doi.org/10.1039/b200623p
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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