The synthesis of organic carbonates from carbon dioxide
Abstract
Carbon dioxide (CO(2)) is an easily available, renewable carbon resource, which has the advantages of being non-toxic, abundant and economical. CO(2) is also attractive as an environmentally friendly chemical reagent, and is especially useful as a phosgene substitute. CO(2) is an "anhydrous carbonic acid" that rapidly reacts with basic compounds. Nucleophilic attack at CO(2) conveniently produces carboxyl and carbamoyl groups. Further reactions of these species with electrophiles lead to the formation of organic carbonates and carbamates. The present article deals with the synthetic technologies leading to organic carbonates using CO(2) as a raw material.
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The thermodynamics of the dehydrative cyclization reaction to cyclic carbonates from CO2 is unfavorable, similar to the synthesis of dialkyl carbonate from CO2.
“The thermodynamics of this dehydrative cyclization reaction is unfavorable, similar to the synthesis of dialkyl carbonate from CO2. 184”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [184]
Organic carbonates can be produced on a large scale from CO, or potentially from CO2.
“They can be produced on a large scale from CO, or potentially from CO2. 183,184”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [184]
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- Authors
- Sakakura, T., & Kohno, K.
- Affiliations
- University of Tsukuba (JP)
- National Institute of Advanced Industrial Science and Technology (JP)
- Corresponding author
- Sakakura, Toshiyasu
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2009
- Issue
- 11
- Pages
- 1312
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2078809665
- Cited by
- 1,067
- References
- 156
- Citations by year
- 2026: 20 · 2025: 24 · 2024: 40 · 2023: 40 · 2022: 42 · 2021: 40 · 2020: 66 · 2019: 70 · 2018: 66 · 2017: 77 · 2016: 77 · 2015: 104 · 2014: 107 · 2013: 81 · 2012: 75
- FWCI
- 46.03
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- CO2 utilization, organic carbonates, carbamates, carboxyl groups, carbamoyl group, electrophilic reactions
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