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Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalystElectronic supplementary information (ESI) available: Levich plots at 1% and 10% hydrogen, and a comparison of the effect of carbon monoxide on oxidation currents obtained at platinum and enzyme-modified electrodes. See http://www.rsc.org/suppdata/cc/b2/b201337a/
Abstract
It is shown that for molecules of Allochromatium vinosum [NiFe]-hydrogenase adsorbed on a pyrolytic graphite electrode the nickel-iron active site catalyzes hydrogen oxidation at a diffusion-controlled rate matching that achieved by platinum.
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Citations
Cited by
Enzymes as Working or Inspirational Electrocatalysts for Fuel Cells and Electrolysis
Cracknell, J. A., Vincent, K. A., & Armstrong, F. A. (2008) · Chemical Reviews · doi:10.1021/cr0680639 · Cited by 988
Self-citationElectro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Léger, C., Jones, A. K., Albracht, S. P. J., & Armstrong, F. A. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0265687 · Cited by 285
Self-citationElectrocatalytic hydrogen oxidation by an enzyme at high carbon monoxide or oxygen levels
Vincent, K. A., Cracknell, J. A., Lenz, O., Zebger, I., Friedrich, B., & Armstrong, F. A. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0504499102 · Cited by 271
Self-citationDas, R. K., Wang, Y., Vasilyeva, S. V., Donoghue, E., Pucher, I., Kamenov, G., Cheng, H.-P., & Rinzler, A. G. (2014) · ACS Nano · doi:10.1021/nn5030225 · Cited by 136
Metadata
- Authors
- Jones, A. K., Sillery, E., Albracht, S. P. J., & Armstrong, F. A.
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002-03-21
- Issue
- 8
- Pages
- 866-867
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W1926852547
- Cited by
- 261
- References
- 0
- FWCI
- 5.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalystElectronic supplementary information (ESI) available: Levich plots at 1% and 10% hydrogen, and a comparison of the effect of carbon monoxide on oxidation currents obtained at platinum and enzyme-modified electrodes. See http://www.rsc.org/suppdata/cc/b2/b201337a/. https://app.cochat.ai/papers/10.1039/b201337a
- The paper
- Jones, A. K., Sillery, E., Albracht, S. P. J., & Armstrong, F. A. (2002). Direct comparison of the electrocatalytic oxidation of hydrogen by an enzyme and a platinum catalystElectronic supplementary information (ESI) available: Levich plots at 1% and 10% hydrogen, and a comparison of the effect of carbon monoxide on oxidation currents obtained at platinum and enzyme-modified electrodes. See http://www.rsc.org/suppdata/cc/b2/b201337a/. Chemical Communications. https://doi.org/10.1039/b201337a
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