The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Ionic liquids based on imidazolium, ammonium and pyrrolidinium salts of the dicyanamide anion
Abstract
New families of salts, based on quaternary ammonium, 1-methyl-3-alkylimidazolium or N-methyl-N-alkylpyrrolidinium organic cations together with the dicyanamide (dca, N(CN)2−) anion are reported. The salts are low melting compounds, all those reported are liquid at room temperature, for example 1-methyl-3-ethylimidazolium dicyanamide (mp −21 °C) and N-methyl-N-ethylpyrrolidinium dicyanamide (mp −10 °C). Some of the salts exhibit multiple crystalline phases below their melting points. Above their melting points they are stable to at least 200 °C. Many of the salts were found to be glass forming when cooled rapidly to −100 °C. The room-temperature liquids exhibit very low viscosities, for example ethylmethylimidazolium dicyanamide: η = 21 cP at ambient temperature (25 °C).
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Cites
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Cited by
How Ionic Are Room-Temperature Ionic Liquids? An Indicator of the Physicochemical Properties
Tokuda, H., Tsuzuki, S., Susan, M. A. B. H., Hayamizu, K., & Watanabe, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp064159v · Cited by 1,206
Application of ionic liquids to the electrodeposition of metals
Abbott, A. P., & McKenzie, K. J. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b607329h · Cited by 817
Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
MacFarlane, D. R., Forsyth, M., Howlett, P. C., Pringle, J. M., Sun, J., Annat, G., Neil, W., & Izgorodina, E. I. (2007) · Accounts of Chemical Research · doi:10.1021/ar7000952 · Cited by 710
Self-citationExtraction of organic compounds with room temperature ionic liquids
Poole, C. F., & Poole, S. K. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.09.011 · Cited by 493
Thermal degradation of cyano containing ionic liquids
Wooster, T. J., Johanson, K. M., Fraser, K. J., MacFarlane, D. R., & Scott, J. L. (2006) · Green Chemistry · doi:10.1039/b606395k · Cited by 255
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Metadata
- Authors
- MacFarlane, D. R., Forsyth, S. A., Golding, J., & Deacon, G. B.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002-07-29
- Volume
- 4
- Issue
- 5
- Pages
- 444-448
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2057708122
- Cited by
- 464
- References
- 1
- FWCI
- 5.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- MacFarlane, D. R., Forsyth, S. A., Golding, J., & Deacon, G. B. (2002). Ionic liquids based on imidazolium, ammonium and pyrrolidinium salts of the dicyanamide anion. Green Chemistry. https://doi.org/10.1039/b205641k
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