Application of ionic liquids to the electrodeposition of metals
Abstract
The electrodeposition of most of technologically important metals has been shown to be possible from a wide range of room temperature molten salts, more commonly known today as 'ionic liquids'. These liquids are currently under intense scrutiny for a wide variety of applications some of which have already been commercialized. Despite the fact that electrodeposition was the first application studied in these liquids no metal deposition processes have as yet been developed to an industrial scale. This review addresses the practical and theoretical aspects that need to be considered when choosing ionic liquids for metal deposition. It details the current understanding of the physical and chemical properties of these interesting fluids and highlights the areas that need to be considered to develop practical electroplating systems. The effect of composition and temperature on viscosity and conductivity are discussed together with the fundamental approaches required to synthesise new liquids.
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Type III eutectics are easy to prepare and relatively unreactive with water; many are biodegradable and of relatively low cost.
“Type III eutectics are easy to prepare and are relatively unreactive with water; many are biodegradable and are of relatively low cost.”
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Electrodeposition from Ionic Liquids
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Application of ionic liquids in hydrometallurgy of nonferrous metals
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On the electrodeposition of nickel–zinc alloys from a eutectic-based ionic liquid
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Deep eutectics and analogues as electrolytes in batteries
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Copper(I)‐Containing Ionic Liquids for High‐Rate Electrodeposition
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Non-classical diffusion in ionic liquids
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Charge Trapping in Imidazolium Ionic Liquids
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- Authors
- Abbott, A. P., & McKenzie, K. J.
- Affiliations
- University of Leicester (GB)
- Corresponding author
- Abbott, Andrew P.
- ORCID
- Abbott, Andrew P.
- Venue
- Physical Chemistry Chemical Physics
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Volume
- 8
- Issue
- 37
- Pages
- 4265
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2014997883
- Cited by
- 817
- References
- 171
- Citations by year
- 2026: 14 · 2025: 17 · 2024: 30 · 2023: 28 · 2022: 74 · 2021: 42 · 2020: 52 · 2019: 41 · 2018: 49 · 2017: 56 · 2016: 52 · 2015: 62 · 2014: 46 · 2013: 55 · 2012: 43
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Physical Chemistry Chemical Physics (publishedVersion)
- PubMed (publishedVersion)
- Leicester Research Archive (University of Leicester) (submittedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Electrodeposition and Electroless Coatings
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Molten salt chemistry and electrochemical processes
- Keywords
- ionic liquids, metal electrodeposition, molten salts, electroplating, viscosity, electrical conductivity, temperature effects, ionic liquid synthesis, room temperature ionic liquids
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