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Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides and methanol using heterogeneous Mg containing smectite catalysts: effect of reaction variables on activity and selectivity performance
Abstract
This paper reports the effect of various reaction variables on the activity and selectivity performance on a two-step synthesis of dimethyl carbonate (DMC) and glycol from propylene oxide, carbon dioxide and methanol using a heterogeneous Mg containing smectite catalyst. The first step, the reaction of propylene oxide with CO2 to form propylene carbonate, and the second step, the transesterification reaction of the cyclic carbonate such as ethylene carbonate with methanol to DMC and ethylene glycol, have been studied. The catalyst was found to be effective for one-pot synthesis of DMC, i.e. the sequential reaction of the epoxide, CO2 and methanol.
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Citations
Cited by
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Multiscale Studies on Ionic Liquids
Dong, K., Liu, X., Dong, H., Zhang, X., & Zhang, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00776 · Cited by 773
Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion
Yang, Z.-Z., He, L.-N., Gao, J., Liu, A.-H., & Yu, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee02774g · Cited by 520
Non-isocyanate polyurethanes: from chemistry to applications
Kathalewar, M. S., Joshi, P. B., Sabnis, A. S., & Malshe, V. C. (2013) · RSC Advances · doi:10.1039/c2ra21938g · Cited by 414
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Metadata
- Authors
- Bhanage, B. M., Fujita, S.-I., Ikushima, Y., Torii, K., & Arai, M.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2002-11-18
- Volume
- 5
- Issue
- 1
- Pages
- 71-75
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2021438419
- Cited by
- 178
- References
- 0
- FWCI
- 6.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides and methanol using heterogeneous Mg containing smectite catalysts: effect of reaction variables on activity and selectivity performance. https://app.cochat.ai/papers/10.1039/b207750g
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- Bhanage, B. M., Fujita, S.-I., Ikushima, Y., Torii, K., & Arai, M. (2003). Synthesis of dimethyl carbonate and glycols from carbon dioxide, epoxides and methanol using heterogeneous Mg containing smectite catalysts: effect of reaction variables on activity and selectivity performance. Green Chemistry. https://doi.org/10.1039/b207750g
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
