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Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate
Abstract
1-Butyl-3-methylimidazolium fluoride hydrate has been identified crystallographically as a decomposition product created during purification of the hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. This highlights the need to treat ionic liquids much as one would any other research chemical with potentially hazardous properties, unknown toxicity and/or stability, particularly when searching for ‘green solvents’.
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Citations
Cited by
Ionic Liquids and Their Interaction with Cellulose
Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369
Self-citationExtraction of organic compounds with room temperature ionic liquids
Poole, C. F., & Poole, S. K. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.09.011 · Cited by 493
Dai, Y., van Spronsen, J., Witkamp, G.-J., Verpoorte, R., & Choi, Y. H. (2013) · Journal of Natural Products · doi:10.1021/np400051w · Cited by 472
INNOVATIVE APPLICATIONS OF IONIC LIQUIDS AS “GREEN” ENGINEERING LIQUIDS
Zhao, H. (2006) · Chemical Engineering Communications · doi:10.1080/00986440600586537 · Cited by 343
Metadata
- Authors
- Swatloski, R. P., Holbrey, J. D., & Rogers, R. D.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003
- Volume
- 5
- Issue
- 4
- Pages
- 361
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2164670414
- Cited by
- 982
- References
- 0
- FWCI
- 18.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Swatloski, R. P., Holbrey, J. D., & Rogers, R. D. (2003). Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate. Green Chemistry. https://doi.org/10.1039/b304400a
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
