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Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate
Abstract
1-Butyl-3-methylimidazolium fluoride hydrate has been identified crystallographically as a decomposition product created during purification of the hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. This highlights the need to treat ionic liquids much as one would any other research chemical with potentially hazardous properties, unknown toxicity and/or stability, particularly when searching for ‘green solvents’.
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Citations
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Dai, Y., van Spronsen, J., Witkamp, G.-J., Verpoorte, R., & Choi, Y. H. (2013) · Journal of Natural Products · doi:10.1021/np400051w · Cited by 472
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Yao, C., Pitner, W. R., & Anderson, J. L. (2009) · Analytical Chemistry · doi:10.1021/ac900719m · Cited by 167
Kuhlmann, E., Himmler, S., Giebelhaus, H., & Wasserscheid, P. (2007) · Green Chem. · doi:10.1039/b611974c · Cited by 150
Khataei, M. M., Yamini, Y., Nazaripour, A., & Karimi, M. (2018) · Talanta · doi:10.1016/j.talanta.2017.09.068 · Cited by 113
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Metadata
- Authors
- Swatloski, R. P., Holbrey, J. D., & Rogers, R. D.
- Venue
- Green Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003
- Volume
- 5
- Issue
- 4
- Pages
- 361
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2164670414
- Cited by
- 982
- References
- 0
- FWCI
- 18.50
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
