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Study on composition, structure and formation process of nanotube Na2Ti2O4(OH)2
Abstract
A nanotube material is obtained by the reaction of polycrystalline TiO2 with concentrated NaOH solution for 20 h at 110 °C. From the contents of Na, Ti and the structural water determined, it is concluded that the nanotube material is Na2Ti2O4(OH)2, rather than TiO2, TiOx or H2TiO3. After treating with an HCl solution of pH 1, nanotube Na2Ti2O4(OH)2 can be converted to nanotube H2Ti2O4(OH)2. The crystalline structure of such nanotube materials belongs to an orthorhombic crystalline system. TEM results indicate that nanotube Na2Ti2O4(OH)2 is formed in the reaction stage of TiO2 with concentrated NaOH solution. The formation process is discussed.
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Cited by
Protonated Titanates and TiO2 Nanostructured Materials: Synthesis, Properties, and Applications
Bavykin, D. V., Friedrich, J. M., & Walsh, F. C. (2006) · Advanced Materials · doi:10.1002/adma.200502696 · Cited by 1,634
Tsai, C.-C., & Teng, H. (2006) · Chemistry of Materials · doi:10.1021/cm0518527 · Cited by 486
Materials Synthesis Insights from Scientific Literature via Text Extraction and Machine Learning
Kim, E., Huang, K., Saunders, A., McCallum, A., Ceder, G., & Olivetti, E. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b03500 · Cited by 473
Vijayan, B., Dimitrijevic, N. M., Rajh, T., & Gray, K. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp104345h · Cited by 124
Metadata
- Authors
- Yang, J., Jin, Z., Wang, X., Li, W., Zhang, J., Zhang, S., Guo, X., & Zhang, Z.
- Venue
- Dalton Transactions
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2003
- Issue
- 20
- Pages
- 3898
- ISSN
- 1477-9226 (ISSN-L)
- 1477-9234
- OpenAlex
- W2030244394
- Cited by
- 478
- References
- 0
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, J., Jin, Z., Wang, X., Li, W., Zhang, J., Zhang, S., Guo, X., & Zhang, Z. (2003). Study on composition, structure and formation process of nanotube Na2Ti2O4(OH)2. Dalton Transactions. https://doi.org/10.1039/b305585j
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