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Tin-free radical chemistry using the persistent radical effect: alkoxyamine isomerization, addition reactions and polymerizations
Abstract
In this tutorial review applications of alkoxyamines as C-radical precursors for the conduction of tin-free radical reactions are presented. These processes are controlled by the Persistent Radical Effect. A brief introduction on the Persistent Radical Effect is provided. In addition, the use of microwave irradiation to conduct thermal radical reactions is discussed. Finally, the use of alkoxyamines as initiators/mediators for the controlled/living radical polymerization is highlighted.
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Citations
Cited by
Dual Catalysis Strategies in Photochemical Synthesis
Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
The recent achievements of redox-neutral radical C–C cross-coupling enabled by visible-light
Xie, J., Jin, H., & Hashmi, A. S. K. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00339k · Cited by 532
Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts
Sumino, S., Fusano, A., Fukuyama, T., & Ryu, I. (2014) · Accounts of Chemical Research · doi:10.1021/ar500035q · Cited by 503
Satoh, K., & Kamigaito, M. (2009) · Chemical Reviews · doi:10.1021/cr900115u · Cited by 302
Metadata
- Authors
- Studer, A.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2004
- Volume
- 033
- Issue
- 5
- Pages
- 267
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2316651929
- Cited by
- 298
- References
- 0
- FWCI
- 4.24
- Type
- journal article
- Language
- en
- Open access
- closed
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