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Metal–Salen Schiff base complexes in catalysis: practical aspects
Abstract
Schiff base ligands are considered "privileged ligands" because they are easily prepared by the condensation between aldehydes and imines. Stereogenic centres or other elements of chirality (planes, axes) can be introduced in the synthetic design. Schiff base ligands are able to coordinate many different metals, and to stabilize them in various oxidation states, enabling the use of Schiff base metal complexes for a large variety of useful catalytic transformations. Practical guidelines for the preparation and use of different Schiff base metal complexes in the field of catalytic transformations are discussed in this tutorial review.
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Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Ligand design for functional metal–organic frameworks
Almeida Paz, F. A., Klinowski, J., Vilela, S. M. F., Tomé, J. P. C., Cavaleiro, J. A. S., & Rocha, J. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15055c · Cited by 855
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Rodríguez-Rodríguez, C., Telpoukhovskaia, M., & Orvig, C. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.008 · Cited by 151
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Huang, H.-Y., Xiong, W., Huang, Y.-T., Li, K., Cai, Z., & Zhu, J.-B. (2023) · Nature Catalysis · doi:10.1038/s41929-023-01001-7 · Cited by 105
Metadata
- Authors
- Cozzi, P. G.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2004
- Volume
- 33
- Issue
- 7
- Pages
- 410-421
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2150829534
- Cited by
- 1,978
- References
- 0
- FWCI
- 1.77
- Type
- journal article
- Language
- en
- Open access
- closed
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