Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 326

The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.

A detailed thermodynamic analysis of [C4mim][BF4] + water as a case study to model ionic liquid aqueous solutions

Rebelo, L. P. N., Najdanovic-Visak, V., Visak, Z. P., Nunes da Ponte, M., Szydlowski, J., Cerdeiriña, C. A., Troncoso, J., Romaní, L., Esperança, J. M. S. S., Guedes, H. J. R., de Sousa, H. C.·2004·Green Chem.
DOI 10.1039/b400374h
Open this paper in CoChat — free account

Abstract

Since determining experimentally a wide variety of thermophysical properties—even for a very small portion of the already known room temperature ionic liquids (and their mixtures and solutions)—is an impossible goal, it is imperative that reliable predictive methods be developed. In turn, these methods might offer us clues to understanding the underlying ion–ion and ion–molecule interactions. 1-Butyl-3-methylimidazolium tetrafluoroborate, one of the most thoroughly investigated ionic liquids, together with water, the greenest of the solvents, have been chosen in this work in order to use their mixtures as a case study to model other, greener, ionic liquid aqueous solutions. We focus our attention both on very simple methodologies that permit one to calculate accurately the mixture's molar volumes and heat capacities as well as more sophisticated theories to predict excess properties, pressure and isotope effects in the phase diagrams, and anomalies in some response functions to criticality, with a minimum of information. In regard to experimental work, we have determined: (a) densities as a function of temperature (278.15 < T/K < 333.15), pressure (1 < p/bar < 600), and composition (0 < xIL < 1), thus also excess molar volumes; (b) heat capacities and excess molar enthalpies as a function of temperature (278.15 < T/K < 333.15) and composition (0 < xIL < 1); and (c) liquid–liquid phase diagrams and their pressure (1 < p/bar < 700) and isotopic (H2O/D2O) dependences. The evolution of some of the aforementioned properties in their approach to the critical region has deserved particular attention.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1039/b400374h

Cites

36 of 36 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 36 references

Cited by

See all 326

Metadata

Authors
Rebelo, L. P. N., Najdanovic-Visak, V., Visak, Z. P., Nunes da Ponte, M., Szydlowski, J., Cerdeiriña, C. A., Troncoso, J., Romaní, L., Esperança, J. M. S. S., Guedes, H. J. R., & de Sousa, H. C.
Venue
Green Chem.
Publisher
Royal Society of Chemistry (RSC)
Published
2004
Volume
6
Issue
8
Pages
369-381
ISSN
  • 1463-9262 (ISSN-L)
  • 1463-9270
DOI
10.1039/b400374h
OpenAlex
W2133787774
Cited by
326
References
36
FWCI
7.16
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: A detailed thermodynamic analysis of [C4mim][BF4] + water as a case study to model ionic liquid aqueous solutions. https://app.cochat.ai/papers/10.1039/b400374h
The paper
Rebelo, L. P. N., Najdanovic-Visak, V., Visak, Z. P., Nunes da Ponte, M., Szydlowski, J., Cerdeiriña, C. A., Troncoso, J., Romaní, L., Esperança, J. M. S. S., Guedes, H. J. R., & de Sousa, H. C. (2004). A detailed thermodynamic analysis of [C4mim][BF4] + water as a case study to model ionic liquid aqueous solutions. Green Chem. https://doi.org/10.1039/b400374h

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.