Cited by 516Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assemblybiodegradable polymer synthesis and properties

Modular synthesis of block copolymers via cycloaddition of terminal azide and alkyne functionalized polymers

Opsteen, Joost A., van Hest, Jan C. M.·2005·Chemical Communications

Abstract

Polymeric building blocks containing terminal azide and alkyne functionalities are prepared via atom transfer radical polymerization (ATRP) and used to modularly synthesize block copolymers via 1,3-dipolar cycloaddition reactions, which are quantitative according to SEC measurements.

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Registry

Crossref · 10.1039/b412930j

Cites

15 of 15 references verified0 citation errors · 0 not checkable

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  • Van Hest et al. synthesized PMMA-b-PEG diblock copolymers via the combination of ATRP and alkyne-azide click reaction.

    “Van Hest et al. synthesized PMMA-b-PEG diblock copolymers via the combination of ATRP and alkyne-azide click reaction, as shown in Figure 4. Terminal alkyne and azide moieties were conveniently introduced via protected functionalized initiators [57].”

    From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [57]

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Authors
Opsteen, J. A., & van Hest, J. C. M.
Affiliations
Radboud University Nijmegen (NL)
Venue
Chemical Communications
Published
2005
Issue
1
Pages
57
ISSN
  • 1359-7345 (ISSN-L)
  • 1364-548X
OpenAlex
W2115713783
Cited by
516
References
15
Citations by year
2026: 5 · 2025: 4 · 2024: 14 · 2023: 11 · 2022: 7 · 2021: 12 · 2020: 8 · 2019: 8 · 2018: 8 · 2017: 14 · 2016: 13 · 2015: 22 · 2014: 33 · 2013: 21 · 2012: 34
FWCI
19.79
Type
journal article
Language
en
Open access
closed
Locations
  • Chemical Communications (publishedVersion)
  • PubMed (publishedVersion)
  • TU/e Research Portal (submittedVersion)
  • Radboud Repository (Radboud University) (submittedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Keywords
block copolymers, 1,3-dipolar cycloaddition, azide-alkyne cycloaddition, atom transfer radical polymerization, modular polymer synthesis

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