Modular synthesis of block copolymers via cycloaddition of terminal azide and alkyne functionalized polymers
Abstract
Polymeric building blocks containing terminal azide and alkyne functionalities are prepared via atom transfer radical polymerization (ATRP) and used to modularly synthesize block copolymers via 1,3-dipolar cycloaddition reactions, which are quantitative according to SEC measurements.
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Van Hest et al. synthesized PMMA-b-PEG diblock copolymers via the combination of ATRP and alkyne-azide click reaction.
“Van Hest et al. synthesized PMMA-b-PEG diblock copolymers via the combination of ATRP and alkyne-azide click reaction, as shown in Figure 4. Terminal alkyne and azide moieties were conveniently introduced via protected functionalized initiators [57].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [57]
Cites
Atom Transfer Radical Polymerization
Matyjaszewski, K. A., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,646 · see citing works
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. M. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,853 · see citing works
Metal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,277 · see citing works
Wu, P., Feldman, A. K., Nugent, A. K., Hawker, C. J., Scheel, A., Voit, B. I., Pyun, J., Fréchet, J. M. J., Sharpless, K. B., & Fokin, V. V. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454078 · Cited by 1,167 · see citing works
Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850 · see citing works
Bodine, K. D., Gin, D. Y., & Gin, M. S. (2004) · Journal of the American Chemical Society · doi:10.1021/ja039374t · Cited by 217 · see citing works
Matyjaszewski, K. A., Nakagawa, Y., & Gaynor, S. G. (1997) · Macromolecular Rapid Communications · doi:10.1002/marc.1997.030181209 · Cited by 182 · see citing works
Coca, S., Paik, H., & Matyjaszewski, K. A. (1997) · Macromolecules · doi:10.1021/ma970637b · Cited by 152 · see citing works
Gitsov, I., Lambrych, K. R., Remnant, V. A., & Pracitto, R. (2000) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/1099-0518(20000801)38:15 · Cited by 88 · see citing works
Zhang, X. K., & Matyjaszewski, K. A. (1999) · Macromolecules · doi:10.1021/ma990551d · Cited by 76 · see citing works
Castle, T. C., Hutchings, L. R., & Khosravi, E. (2004) · Macromolecules · doi:10.1021/ma030418s · Cited by 51 · see citing works
Baek, K., Kamigaito, M., & Sawamoto, M. (2002) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.10280 · Cited by 44 · see citing works
Notestein, J. M., Lee, L.-B. W., & Register, R. A. (2002) · Macromolecules · doi:10.1021/ma012157x · Cited by 37 · see citing works
Miura, Y., Sakai, Y., & Taniguchi, I. (2002) · Polymer · doi:10.1016/s0032-3861(02)00785-1 · Cited by 19 · see citing works
Rostovtsev, V. V., Green, L. G., Fokin, V. V., & Sharpless, K. B. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020715)41:14
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Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863 · see citing works
Block Copolymers: Synthesis, Self-Assembly, and Applications
Feng, H., Lu, X., Wang, W., Kang, N.-G., & Mays, J. (2017) · Polymers · doi:10.3390/polym9100494 · Cited by 467 · see citing works
“Terminal alkyne and azide moieties were conveniently introduced via protected functionalized initiators [57].”
BackgroundInglis, A. J., Sinnwell, S., Davis, T. P., Barner-Kowollik, C., & Stenzel, M. H. (2008) · Macromolecules · doi:10.1021/ma8002328 · Cited by 172 · see citing works
- Authors
- Opsteen, J. A., & van Hest, J. C. M.
- Affiliations
- Radboud University Nijmegen (NL)
- Venue
- Chemical Communications
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 1
- Pages
- 57
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2115713783
- Cited by
- 516
- References
- 15
- Citations by year
- 2026: 5 · 2025: 4 · 2024: 14 · 2023: 11 · 2022: 7 · 2021: 12 · 2020: 8 · 2019: 8 · 2018: 8 · 2017: 14 · 2016: 13 · 2015: 22 · 2014: 33 · 2013: 21 · 2012: 34
- FWCI
- 19.79
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Communications (publishedVersion)
- PubMed (publishedVersion)
- TU/e Research Portal (submittedVersion)
- Radboud Repository (Radboud University) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- block copolymers, 1,3-dipolar cycloaddition, azide-alkyne cycloaddition, atom transfer radical polymerization, modular polymer synthesis
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