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Metal–organic rotaxane frameworks; MORFs
Abstract
Linear exodentate pyridinium ligands such as 1,2-bis(4,4'-bipyridinium)ethane or its bis N-oxide derivative can be used as axles for the formation of [2]pseudorotaxanes utilising 24-membered crown ethers such as dibenzo-24-crown-8 ether (DB24C8) as the wheel. These [2]pseudorotaxanes can be used to construct coordination networks using transition or lanthanide metal ions as the connecting nodes. 1-, 2- and 3D metal-organic rotaxane frameworks (MORFs) are possible. The resulting materials contain mechanically interlocked units and may be the forerunners of unique solids which contain machine-like components in an ordered array.
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Citations
Cited by
Yan, X., Xu, D., Chi, X., Chen, J., Dong, S., Ding, X., Yu, Y., & Huang, F. (2012) · Advanced Materials · doi:10.1002/adma.201103220 · Cited by 697
Mechanically interlocked materials. Rotaxanes and catenanes beyond the small molecule
Mena-Hernando, S., & Pérez, E. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00888d · Cited by 303
Metadata
- Authors
- Loeb, S. J.
- Venue
- Chem. Commun.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2005
- Issue
- 12
- Pages
- 1511-1518
- ISSN
- 1359-7345 (ISSN-L)
- 1364-548X
- OpenAlex
- W2165357564
- Cited by
- 232
- References
- 0
- FWCI
- 9.13
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
