Cited by 697Supramolecular Self-Assembly in MaterialsSupramolecular Chemistry and ComplexesHydrogels: synthesis, properties, applications

A Multiresponsive, Shape‐Persistent, and Elastic Supramolecular Polymer Network Gel Constructed by Orthogonal Self‐Assembly

Yan, Xuzhou, Xu, Donghua, Chi, Xiaodong, Chen, Jianzhuang, Dong, Shengyi, Ding, Xia, Yu, Yihua, Huang, Feihe·2012·Advanced Materials

Abstract

A cross-linked supramolecular polymer network gel is designed and prepared, which shows reversible gel-sol transitions induced by changes in pH, temperature, cation concentration, and metal co-ordination. The gel pore size is controlled by the amount of cross-linker added to the system, and the material can be molded into shape-persistent, free-standing objects with elastic behavior. These features are all due to the dynamically reversible host-guest complexation and good mechanical properties of the cross-linked polymer network. No single organogel has previously been reported to possess all of these features, making this supramolecular gel an unprecedentedly intelligent soft material.

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Crossref · 10.1002/adma.201103220

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107 of 107 references verified0 citation errors · 0 not checkable

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  • Another type of photoactive SMP is based on the metal-ligand coordinative interactions of metallosupramolecular networks.

    “Another type of photoactive SMP is based on the metaleligand coordinative interactions of metallosupramolecular networks [115].”

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Authors
Yan, X., Xu, D., Chi, X., Chen, J., Dong, S., Ding, X., Yu, Y., & Huang, F.
Affiliations
  • Zhejiang University (CN)
  • Chinese Academy of Sciences (CN)
  • East China Normal University (CN)
Corresponding author
Huang, Feihe
Venue
Advanced Materials
Publisher
Wiley
Published
2011-12-12
Volume
24
Issue
3
Pages
362-369
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2124662786
Cited by
697
References
107
Citations by year
2026: 8 · 2025: 8 · 2024: 13 · 2023: 16 · 2022: 25 · 2021: 29 · 2020: 35 · 2019: 37 · 2018: 58 · 2017: 58 · 2016: 77 · 2015: 75 · 2014: 128 · 2013: 93 · 2012: 34
FWCI
33.50
Type
journal article
Language
en
Open access
closed
Locations
  • Advanced Materials (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › Supramolecular Self-Assembly in Materials
  • Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
  • Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
Keywords
supramolecular polymer networks, organogels, host-guest complexation, orthogonal self-assembly, elastic gels, pH-responsive, temperature-responsive, metal coordination, crosslinking, soft materials
MeSH terms
Elasticity, Gels, Hydrogen-Ion Concentration, Polymers, Temperature

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