A Multiresponsive, Shape‐Persistent, and Elastic Supramolecular Polymer Network Gel Constructed by Orthogonal Self‐Assembly
Abstract
A cross-linked supramolecular polymer network gel is designed and prepared, which shows reversible gel-sol transitions induced by changes in pH, temperature, cation concentration, and metal co-ordination. The gel pore size is controlled by the amount of cross-linker added to the system, and the material can be molded into shape-persistent, free-standing objects with elastic behavior. These features are all due to the dynamically reversible host-guest complexation and good mechanical properties of the cross-linked polymer network. No single organogel has previously been reported to possess all of these features, making this supramolecular gel an unprecedentedly intelligent soft material.
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Another type of photoactive SMP is based on the metal-ligand coordinative interactions of metallosupramolecular networks.
“Another type of photoactive SMP is based on the metaleligand coordinative interactions of metallosupramolecular networks [115].”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [115]
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- Authors
- Yan, X., Xu, D., Chi, X., Chen, J., Dong, S., Ding, X., Yu, Y., & Huang, F.
- Affiliations
- Zhejiang University (CN)
- Chinese Academy of Sciences (CN)
- East China Normal University (CN)
- Corresponding author
- Huang, Feihe
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2011-12-12
- Volume
- 24
- Issue
- 3
- Pages
- 362-369
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2124662786
- Cited by
- 697
- References
- 107
- Citations by year
- 2026: 8 · 2025: 8 · 2024: 13 · 2023: 16 · 2022: 25 · 2021: 29 · 2020: 35 · 2019: 37 · 2018: 58 · 2017: 58 · 2016: 77 · 2015: 75 · 2014: 128 · 2013: 93 · 2012: 34
- FWCI
- 33.50
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › Supramolecular Self-Assembly in Materials
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Medicine › Hydrogels: synthesis, properties, applications
- Keywords
- supramolecular polymer networks, organogels, host-guest complexation, orthogonal self-assembly, elastic gels, pH-responsive, temperature-responsive, metal coordination, crosslinking, soft materials
- MeSH terms
- Elasticity, Gels, Hydrogen-Ion Concentration, Polymers, Temperature
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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