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Solvent-free synthesis of a microporous metal–organic framework
Abstract
We describe the first solvent-free mechanochemical synthesis of a microporous metal–organic framework [Cu(INA)2] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating—the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal–organic frameworks (MOFs).
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Cited by
New synthetic routes towards MOF production at scale
Rubio-Martinez, M., Avci-Camur, C., Thornton, A. W., Imaz, I., Maspoch, D., & Hill, M. R. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00109f · Cited by 990
Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Recent advances in crystal engineering
Aakeröy, C. B., Champness, N. R., & Janiak, C. (2010) · CrystEngComm · doi:10.1039/b919819a · Cited by 746
Metal-organic frameworks for advanced drug delivery
He, S., Wu, L., Li, X., Sun, H., Xiong, T., Liu, J., Huang, C., Xu, H., Sun, H., Chen, W., et al. (2021) · Acta Pharmaceutica Sinica B · doi:10.1016/j.apsb.2021.03.019 · Cited by 528
Covalent Chemistry beyond Molecules
Jiang, J., Zhao, Y., & Yaghi, O. M. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10666 · Cited by 448
Metadata
- Authors
- Pichon, A., Lazuen-Garay, A., & James, S. L.
- Venue
- CrystEngComm
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Volume
- 8
- Issue
- 3
- Pages
- 211
- ISSN
- 1466-8033 (ISSN-L)
- OpenAlex
- W2044614763
- Cited by
- 665
- References
- 0
- FWCI
- 8.27
- Type
- journal article
- Language
- en
- Open access
- closed
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