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On the temperature stability of gold nanorods: comparison between thermal and ultrafast laser-induced heating
Abstract
The response of gold nanorods to both thermal and ultrafast laser-induced heating has been examined. The thermal heating experiments show structural changes that occur on timescales ranging from hours to days. At the highest temperature examined (250 degrees C) the nanorods are transformed into spheres within an hour. On the other hand, no structural changes are observed in the laser-induced heating experiments up to temperatures of 700 +/- 50 degrees C. This is attributed to thermal diffusion in the laser experiments. Measurements of the period of the extensional mode of the nanorods using time-resolved spectroscopy show a significant softening at high pump laser powers. However, the decrease in the period is less than expected from bulk Young's modulus vs. temperature data.
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Cites
Optical Constants of the Noble Metals
Johnson, P. B., & Christy, R. W. (1972) · Physical Review B · doi:10.1103/physrevb.6.4370 · Cited by 20,094
Haes, A. J., & Van Duyne, R. P. (2002) · Journal of the American Chemical Society · doi:10.1021/ja020393x · Cited by 2,057
Cited by
Tuning Size and Sensing Properties in Colloidal Gold Nanostars
Barbosa, S., Agrawal, A., Rodríguez-Lorenzo, L., Pastoriza-Santos, I., Alvarez-Puebla, R. A., Kornowski, A., Weller, H., & Liz-Marzán, L. M. (2010) · Langmuir · doi:10.1021/la102559e · Cited by 522
Self-citationUltrafast Thermal Analysis of Surface Functionalized Gold Nanorods in Aqueous Solution
Huang, J., Park, J., Wang, W., Murphy, C. J., & Cahill, D. G. (2013) · ACS Nano · doi:10.1021/nn304738u · Cited by 83
Transformation of Gold Nanorods in Liquid Media Induced by nIR, Visible, and UV Laser Irradiation
Attia, Y. A., Flores-Arias, M. T., Nieto, D., Vázquez-Vázquez, C., De La Fuente, G. F., & López-Quintela, M. A. (2015) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b03046 · Cited by 16
Metadata
- Authors
- Petrova, H., Perez Juste, J., Pastoriza-Santos, I., Hartland, G. V., Liz-Marzán, L. M., & Mulvaney, P.
- Venue
- Phys. Chem. Chem. Phys.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2006
- Volume
- 8
- Issue
- 7
- Pages
- 814-821
- ISSN
- 1463-9076 (ISSN-L)
- 1463-9084
- OpenAlex
- W2038841077
- Cited by
- 313
- References
- 2
- FWCI
- 4.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Petrova, H., Perez Juste, J., Pastoriza-Santos, I., Hartland, G. V., Liz-Marzán, L. M., & Mulvaney, P. (2006). On the temperature stability of gold nanorods: comparison between thermal and ultrafast laser-induced heating. Phys. Chem. Chem. Phys. https://doi.org/10.1039/b514644e
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