The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties
Abstract
Palladium was infiltrated into the highly porous metal–organic framework MOF-5 {[Zn4O(bdc)3], bdc = benzene-1,4-dicarboxylate} using [Pd(acac)2] (acac = acetylacetonate) as the precursor in chloroform solution via ‘incipient wetness’ impregnation. The specific surface area decreases from 2885 m2 g−1 to 958 m2 g−1 after infiltration. After reduction in hydrogen or under vacuum, the hydrogen adsorption capacity is increased from 1.15 wt% to 1.86 wt% at 1 atm and 77 K. The palladium loaded MOF-5 has a high catalytic activity in styrene hydrogenation comparable to that of palladium on activated carbon, but cis-cyclooctene hydrogenation is considerably slower. Even at room temperature, the catalyst is not stable in air due to the low hydrothermal stability of the MOF-5 support.
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Cites
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Cited by
The Chemistry and Applications of Metal-Organic Frameworks
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Metal-organic frameworks: structure, properties, methods of synthesis and characterization
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Metadata
- Authors
- Sabo, M., Henschel, A., Fröde, H., Klemm, E., & Kaskel, S.
- Venue
- Journal of Materials Chemistry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Volume
- 17
- Issue
- 36
- Pages
- 3827
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2011415218
- Cited by
- 489
- References
- 20
- FWCI
- 22.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sabo, M., Henschel, A., Fröde, H., Klemm, E., & Kaskel, S. (2007). Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic properties. Journal of Materials Chemistry. https://doi.org/10.1039/b706432b
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