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Desulfurisation of oils using ionic liquids: selection of cationic and anionic components to enhance extraction efficiency
Abstract
Extraction of dibenzothiophene from dodecane using ionic liquids as the extracting phase has been investigated for a range of ionic liquids with varying cation classes (imidazolium, pyridinium, and pyrrolidinium) and a range of anion types using liquid–liquid partition studies and QSPR (quantitative structure–activity relationship) analysis. The partition ratio of dibenzothiophene to the ionic liquids showed a clear variation with cation class (dimethylpyridinium > methylpyridinium > pyridinium ≈ imidazolium ≈ pyrrolidinium), with much less significant variation with anion type. Polyaromatic quinolinium-based ionic liquids showed even greater extraction potential, but were compromised by higher melting points. For example, 1-butyl-6-methylquinolinium bis{(trifluoromethyl)sulfonyl}amide (mp 47 °C) extracted 90% of the available dibenzothiophene from dodecane at 60 °C.
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Cited by
Ionic liquids in analytical chemistry
Sun, P., & Armstrong, D. W. (2010) · Analytica Chimica Acta · doi:10.1016/j.aca.2009.12.007 · Cited by 727
Energy applications of ionic liquids
Wishart, J. F. (2009) · Energy & Environmental Science · doi:10.1039/b906273d · Cited by 502
Extraction of organic compounds with room temperature ionic liquids
Poole, C. F., & Poole, S. K. (2010) · Journal of Chromatography A · doi:10.1016/j.chroma.2009.09.011 · Cited by 493
Dai, Y., van Spronsen, J., Witkamp, G.-J., Verpoorte, R., & Choi, Y. H. (2013) · Journal of Natural Products · doi:10.1021/np400051w · Cited by 472
Metadata
- Authors
- Holbrey, J. D., López-Martin, I., Rothenberg, G., Seddon, K. R., Silvero, G., & Zheng, X.
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 1
- Pages
- 87-92
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2151832062
- Cited by
- 241
- References
- 0
- FWCI
- 7.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Holbrey, J. D., López-Martin, I., Rothenberg, G., Seddon, K. R., Silvero, G., & Zheng, X. (2008). Desulfurisation of oils using ionic liquids: selection of cationic and anionic components to enhance extraction efficiency. Green Chem. https://doi.org/10.1039/b710651c
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.