Ionic liquids in analytical chemistry
Abstract
Ionic liquids (ILs) are composed entirely of ions and they possess fascinating properties, including low volatility, tunable viscosity and miscibility, and electrolytic conductivity, which make ILs unique and useful for many applications in chemical analysis. The dramatic increase in the number of publications on ILs is indicative of the tremendous interest in this field from analytical chemists. This review summarizes recent efforts in the major subdisciplines of analytical chemistry, including extractions, gas chromatography, liquid chromatography, capillary electrophoresis, mass spectrometry, electrochemistry, sensors, and spectroscopy.
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Conventional extraction procedures are often time-consuming, tedious and multistage, and liquid-liquid phase extraction consumes a large amount of potentially hazardous organic solvents.
“However, conventional extraction procedures are often time-consuming, tedious and multistage operations, and the liquid-liquid phase extraction consumes a large amount of potentially hazardous organic solvents [18,23].”
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Sorted by citations
Gałuszka, A., Migaszewski, Z., & Namieśnik, J. (2013) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2013.04.010 · Cited by 2,461 · see citing works
Ionic liquids and deep eutectic mixtures: Sustainable solvents for extraction processes
Pena‐Pereira, F., & Namieśnik, J. (2014) · ChemSusChem · doi:10.1002/cssc.201301192 · Cited by 432 · see citing works
Rykowska, I., Ziemblińska, J., & Nowak, I. (2018) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2018.03.043 · Cited by 353 · see citing works
Ionic liquids in dispersive liquid-liquid microextraction
Trujillo-Rodríguez, M. J., Rocío-Bautista, P., Pino, V., & Afonso, A. M. (2013) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2013.06.008 · Cited by 276 · see citing works
Karimi, M., Dadfarnia, S., Shabani, A. M. H., Tamaddon, F., & Azadi, D. (2015) · Talanta · doi:10.1016/j.talanta.2015.07.021 · Cited by 182 · see citing works
Application of ionic liquids in microextraction techniques: Current trends and future perspectives
Marcinkowska, R., Konieczna, K., Marcinkowski, Ł., Namieśnik, J., & Kloskowski, A. (2019) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2019.07.025 · Cited by 119 · see citing works
Application of ionic liquid in liquid phase microextraction technology
Han, D., Tang, B., Ri Lee, Y., & Ho Row, K. (2012) · Journal of Separation Science · doi:10.1002/jssc.201200486 · Cited by 103 · see citing works
Recent Advances in Applications of Ionic Liquids in Miniaturized Microextraction Techniques
Kissoudi, M., & Samanidou, V. (2018) · Molecules · doi:10.3390/molecules23061437 · Cited by 86 · see citing works
Ionic liquids in microextraction techniques
Vičkačkaitė, V., & Padarauskas, A. (2012) · Open Chemistry · doi:10.2478/s11532-012-0023-4 · Cited by 84 · see citing works
Thongsaw, A., Udnan, Y., Ross, G. M., & Chaiyasith, W. C. (2019) · Talanta · doi:10.1016/j.talanta.2019.01.018 · Cited by 73 · see citing works
Seebunrueng, K., Dejchaiwatana, C., Santaladchaiyakit, Y., & Srijaranai, S. (2017) · RSC Adv. · doi:10.1039/c7ra07780g · Cited by 39 · see citing works
Sun, X.-L., Zhou, W., Gu, L., Qiu, D., Ren, D.-H., Gu, Z.-G., & Li, Z. (2015) · Journal of Nuclear Science and Technology · doi:10.1080/00223131.2014.946454 · Cited by 43 · see citing works
Shah, F., Soylak, M., Kazi, T. G., & Afridi, H. I. (2012) · Journal of Analytical Atomic Spectrometry · doi:10.1039/c2ja30243h · Cited by 40 · see citing works
Vidal, L., Silva, S. G., Canals, A., & Nóbrega, J. A. (2016) · Talanta · doi:10.1016/j.talanta.2015.04.023 · Cited by 29 · see citing works
- Authors
- Sun, P., & Armstrong, D. W.
- Affiliations
- The University of Texas at Arlington (US)
- Corresponding author
- Armstrong, Daniel W.
- ORCID
- Armstrong, Daniel W.
- Venue
- Analytica Chimica Acta
- Publisher
- Elsevier BV
- Published
- 2010-02
- Volume
- 661
- Issue
- 1
- Pages
- 1-16
- ISSN
- 0003-2670 (ISSN-L)
- OpenAlex
- W3025840125
- Cited by
- 727
- References
- 0
- Citations by year
- 2026: 7 · 2025: 9 · 2024: 28 · 2023: 27 · 2022: 32 · 2021: 26 · 2020: 33 · 2019: 36 · 2018: 39 · 2017: 64 · 2016: 45 · 2015: 67 · 2014: 79 · 2013: 72 · 2012: 81
- FWCI
- 21.92
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Analytica Chimica Acta (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Welch Foundation
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Keywords
- ionic liquids, extraction, gas chromatography, liquid chromatography, capillary electrophoresis, mass spectrometry, electrochemistry, sensors, spectroscopy, miscibility, electrolyte conductivity
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