The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Abstract
A series of alkylimidazolium salts containing dimethyl phosphate, methyl methylphosphonate, or methyl phosphonate prepared by a facile, one-pot procedure were obtained as room temperature ionic liquids, which have the potential to solubilize cellulose under mild conditions. Especially, N-ethyl-N′-methylimidazolium methylphosphonate enables the preparation of 10 wt% cellulose solution by keeping it at 45 °C for 30 min with stirring and rendered soluble 2–4 wt% cellulose without pretreatments and heating.
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“Cellulose dissolution is an industrially attractive application of ionic liquids, due to good solubilities (5-20 wt%, depending on the ionic liquid and the conditions), the competitive properties of cellulose reprecipitated from the ionic liquid solutions, 73 the increased stability of ionic liquid cellulose solutions 74 and the low toxicity of certain relevant ionic liquids (for example, [C 2 C 1”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [73]
Citations
Cites
Dissolution of Cellose with Ionic Liquids
Swatloski, R. P., Spear, S. K., Holbrey, J. D., & Rogers, R. D. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025790m · Cited by 4,735
Zhang, H., Wu, J. L., Zhang, J., & He, J. (2005) · Macromolecules · doi:10.1021/ma0505676 · Cited by 1,437
Electrochemical aspects of ionic liquids
(2005) · Choice Reviews Online · doi:10.5860/choice.43-1569 · Cited by 1,208
Rapid Dissolution of Cellulose in LiOH/Urea and NaOH/Urea Aqueous Solutions
Cai, J., & Zhang, L. (2005) · Macromolecular Bioscience · doi:10.1002/mabi.200400222 · Cited by 1,061
Solvent–solute interactions in ionic liquids
Crowhurst, L., Mawdsley, P. R., Perez‐Arlandis, J. M., Salter, P. A., & Welton, T. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b303095d · Cited by 776
Remsing, R. C., Swatloski, R. P., Rogers, R. D., & Moyna, G. (2006) · Chemical Communications · doi:10.1039/b600586c · Cited by 712
Solution studies of cellulose in lithium chloride and N,N-dimethylacetamide
McCormick, C. L., Callais, P. A., & Hutchinson, B. H. (1985) · Macromolecules · doi:10.1021/ma00154a010 · Cited by 683
Armstrong, D. W., He, L., & Liu, Y.-S. (1999) · Analytical Chemistry · doi:10.1021/ac990443p · Cited by 623
Fukaya, Y., Sugimoto, A., & Ohno, H. (2006) · Biomacromolecules · doi:10.1021/bm060327d · Cited by 509
Self-citationDissolution and Regeneration of Bombyx mori Silk Fibroin Using Ionic Liquids
Phillips, D. M., Drummy, L. F., Conrady, D. G., Fox, D. M., Naik, R. R., Stone, M. O., Trulove, P. C., Long, H. C. D., & Mantz, R. A. (2004) · Journal of the American Chemical Society · doi:10.1021/ja046079f · Cited by 479
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Research works printed but not linked: 3
- Cellulose Derivatives Modification, Characterization, and Nanostructures, ACS Symposium Series 688, eds. T. H. Heinze and W. G. Glasser, American Chemical Society, Washington, DC, 1997
- Ionic Liquids in Synthesis, eds. P. Wasserscheid and T. Welton, Wiley-VCH, Weinheim, Germany, 2003
- A. J. Carmichael , M.Deetlefs, M. J.Earle, U.Frohlich and K.Seddon, in Ionic Liquids as Green Solvents, Progress and Prospects, ACS Symposium Series 856, eds. R. D. Rogers and K. R. Seddon, American Chemical Society, Washington, 2003, pp 14–31
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Ionic-liquid materials for the electrochemical challenges of the future
Armand, M. B., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009) · Nature Materials · doi:10.1038/nmat2448 · Cited by 4,694
Self-citationIonic liquids and catalysis: Recent progress from knowledge to applications
Olivier‐Bourbigou, H., Magna, L., & Morvan, D. L. (2009) · Applied Catalysis A General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,671
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
Ionic Liquids and Their Interaction with Cellulose
Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369
Metadata
- Authors
- Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H.
- Affiliations
- Tokyo University of Agriculture and Technology (JP)
- The University of Tokyo (JP)
- Corresponding author
- Ohno, Hiroyuki
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 1
- Pages
- 44-46
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1980836177
- Cited by
- 775
- References
- 23
- Citations by year
- 2026: 12 · 2025: 14 · 2024: 20 · 2023: 15 · 2022: 30 · 2021: 24 · 2020: 33 · 2019: 60 · 2018: 42 · 2017: 67 · 2016: 50 · 2015: 58 · 2014: 75 · 2013: 58 · 2012: 63
- FWCI
- 13.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
- Keywords
- cellulose dissolution, room temperature ionic liquids, anion effects, dimethyl phosphate, cellulose solubilization, cellulose solutions
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