The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Abstract
A series of alkylimidazolium salts containing dimethyl phosphate, methyl methylphosphonate, or methyl phosphonate prepared by a facile, one-pot procedure were obtained as room temperature ionic liquids, which have the potential to solubilize cellulose under mild conditions. Especially, N-ethyl-N′-methylimidazolium methylphosphonate enables the preparation of 10 wt% cellulose solution by keeping it at 45 °C for 30 min with stirring and rendered soluble 2–4 wt% cellulose without pretreatments and heating.
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“Cellulose dissolution is an industrially attractive application of ionic liquids, due to good solubilities (5-20 wt%, depending on the ionic liquid and the conditions), the competitive properties of cellulose reprecipitated from the ionic liquid solutions, 73 the increased stability of ionic liquid cellulose solutions 74 and the low toxicity of certain relevant ionic liquids (for example, [C 2 C 1”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [73]
Citations
Cites
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Self-citationDissolution and Regeneration of Bombyx mori Silk Fibroin Using Ionic Liquids
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Tetraalkylphosphonium-based ionic liquids
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Allylimidazolium Halides as Novel Room Temperature Ionic Liquids
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Self-citationHimmler, S., Hörmann, S., van Hal, R., Schulz, P. S., & Wasserscheid, P. (2006) · Green Chemistry · doi:10.1039/b601583b · Cited by 77
SEC–MALLS analysis of cellulose using LiCl/1,3-dimethyl-2-imidazolidinone as an eluent
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Research works printed but not linked: 3
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Cited by
Sorted by citations
Ionic-liquid materials for the electrochemical challenges of the future
Armand, M. B., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009) · Nature Materials · doi:10.1038/nmat2448 · Cited by 4,694
Self-citationIonic liquids and catalysis: Recent progress from knowledge to applications
Olivier‐Bourbigou, H., Magna, L., & Morvan, D. L. (2009) · Applied Catalysis A General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,671
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557
Ionic Liquids and Their Interaction with Cellulose
Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369
Metadata
- Authors
- Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H.
- Affiliations
- Tokyo University of Agriculture and Technology (JP)
- The University of Tokyo (JP)
- Corresponding author
- Ohno, Hiroyuki
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 1
- Pages
- 44-46
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1980836177
- Cited by
- 775
- References
- 23
- Citations by year
- 2026: 12 · 2025: 14 · 2024: 20 · 2023: 15 · 2022: 30 · 2021: 24 · 2020: 33 · 2019: 60 · 2018: 42 · 2017: 67 · 2016: 50 · 2015: 58 · 2014: 75 · 2013: 58 · 2012: 63
- FWCI
- 13.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Ionic liquids properties and applications
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis for Biomass Conversion
- Keywords
- cellulose dissolution, room temperature ionic liquids, anion effects, dimethyl phosphate, cellulose solubilization, cellulose solutions
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