An alternative data acquisition and evaluation strategy for improved isotope ratio precision using LA-MC-ICP-MS applied to stable and radiogenic strontium isotopes in carbonates
Abstract
Strontium isotopes in various marine carbonates were determined using an “AXIOM” MC-ICP-MS in combination with a NewWave UP193 laser ablation unit. Using a modified measurement and data reduction strategy, an external reproducibility of 87Sr/86Sr ratios in carbonates of about 19 ppm (RSD) was achieved. For recent and sub-recent marine carbonates a mean radiogenic strontium isotope ratio 87Sr/86Sr of 0.709170 ± 0.000007 (2SE) was determined, which agrees well with the value of 0.7091741 ± 0.0000024 (2SE) reported for modern sea water (J. M. McArthur, D. Rio, F. Massari, D. Castrodi, T. R. Bailey, M. Thirlwall and S. Houghton, Palaeogeogr. Palaeoclimatol. Palaeoeco., 2006, 242(126), 2006). Compared to published laser-based methods, an improved accuracy and precision was achieved by applying a new data reduction protocol using the simultaneous responses of all isotopes measured. The latter is considered as a new principal approach for isotope ratio evaluation using LA-MC-ICP-MS. A major advantage of the presented method is the direct determination of the stable strontium isotope fractionation. Providing reproducible sample ablation, introduction into the plasma and stable plasma condition, this method excludes the efforts of a quantitative strontium recovery after ion chromatographic separation to avoid additional fractionation of the sample strontium due to chemical pre-treatment/separation (ion chromatography and solution preparation), and is therefore, together with the quicker sample preparation and spatially resolved analysis, advantageous when compared to published solution–nebulization bracketing-standard MC-ICP-MS methods for stable strontium isotope determination.
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Collecting only necessary data limits data for certain analyses.
“Limited data for certain analyses”
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Collecting only necessary data reduces data collection and storage costs.
“Reduces data collection and storage costs”
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- Authors
- Fietzke, J., Liebetrau, V., Günther, D., Gürs, K., Hametner, K., Zumholz, K., Hansteen, T. H., & Eisenhauer, A.
- Affiliations
- GEOMAR Helmholtz Centre for Ocean Research Kiel (DE)
- ETH Zurich (CH)
- Corresponding author
- Fietzke, J.
- Venue
- Journal of Analytical Atomic Spectrometry
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 23
- Issue
- 7
- Pages
- 955
- ISSN
- 0267-9477 (ISSN-L)
- 1364-5544
- OpenAlex
- W1984571476
- Cited by
- 133
- References
- 21
- Citations by year
- 2025: 8 · 2024: 6 · 2023: 9 · 2022: 13 · 2021: 9 · 2020: 8 · 2019: 5 · 2018: 11 · 2017: 8 · 2016: 12 · 2015: 8 · 2014: 8 · 2013: 4 · 2012: 10
- FWCI
- 4.22
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Analytical Atomic Spectrometry (publishedVersion)
- Helmholtz Centre for Ocean Research Kiel (GEOMAR) (acceptedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geophysics › Geological and Geochemical Analysis
- Physical Sciences › Chemistry › Analytical Chemistry › Analytical chemistry methods development
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Keywords
- strontium isotopes, 87Sr/86Sr, marine carbonates, laser ablation, MC-ICP-MS, isotope ratio precision, data reduction, stable isotope fractionation, radiogenic strontium
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