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Ionic liquids as amphiphile self-assembly media
Open accessAbstract
In recent years, the number of non-aqueous solvents which mediate hydrocarbon-solvent interactions and promote the self-assembly of amphiphiles has been markedly increased by the reporting of over 30 ionic liquids which possess this previously unusual solvent characteristic. This new situation allows a different exploration of the molecular "solvophobic effect" and tests the current understanding of amphiphile self-assembly. Interestingly, both protic and aprotic ionic liquids support amphiphile self-assembly, indicating that it is not required for the solvents to be able to form a hydrogen bonded network. Here, the use of ionic liquids as amphiphile self-assembly media is reviewed, including micelle and liquid crystalline mesophase formation, their use as a solvent phase in microemulsions and emulsions, and the emerging field of nanostructured inorganic materials synthesis. Surfactants, lipids and block co-polymers are the focus amphiphile classes in this critical review (174 references).
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Ionic liquids: solvent properties and organic reactivity
Chiappe, C., & Pieraccini, D. (2005) · Journal of Physical Organic Chemistry · doi:10.1002/poc.863 · Cited by 1,169
Cited by
Improvements in the Enzymatic Degradation of Textile Dyes Using Ionic- Liquid-Based Surfactants
Bento, R. M. F., Almeida, M. R., Bharmoria, P., Freire, M. G., & Tavares, A. P. M. (2020) · Separation and Purification Technology · doi:10.1016/j.seppur.2019.116191 · Cited by 78
Ghazali, H. S., Askari, E., Seyfoori, A., & Naghib, S. M. (2023) · Scientific Reports · doi:10.1038/s41598-023-35865-3 · Cited by 40
Metadata
- Authors
- Greaves, T. L., & Drummond, C. J.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 37
- Issue
- 8
- Pages
- 1709
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W1990178568
- Cited by
- 532
- References
- 1
- FWCI
- 1.09
- Type
- journal article
- Language
- en
- Open access
- green
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